[Fe(CO)3(η-N(C6H5)=CH-CH=CHPh)]

Base Information

• Chemical Name: [Fe(CO)3(η-N(C6H5)=CH-CH=CHPh)]
• CAS No.: 12112-97-9
• Molecular Formula: C₁₈H₁₃FeNO₃
• Molecular Weight: 347.153
• Mol file: 12112-97-9.mol

Synonyms:

Chemical Property of [Fe(CO)3(η-N(C6H5)=CH-CH=CHPh)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Fe(CO)3(η-N(C6H5)=CH-CH=CHPh)]

There total 6 articles about [Fe(CO)3(η-N(C6H5)=CH-CH=CHPh)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

(η2-PhCH=CHCHO)Fe(CO)4 (866123-02-6,866123-01-5,38720-32-0,12289-03-1,63700-23-2) → tricarbonyl[(1-4-η)-1,4-diphenyl-1-azabuta-1,3-diene]iron (12112-97-9)

Guidance literature:

With aniline; In tetrahydrofuran; byproducts: C6H5CHCHCHNC6H5, Fe(CO)5; addn. of aniline via syringe drop-by-drop; stirring for 2.5 h at room temp.; filtered through silica gel; concd.; sepd. on silica gel with hexane/benzene as eluent; evapn.;

DOI:10.1016/0022-328X(90)80203-C

Reference yield:

[Fe(CO)4(N(C6H5)=CH-CH=CHPh)] → iron pentacarbonyl (13463-40-6,37220-42-1) + [Fe(CO)3(η-N(C6H5)=CH-CH=CHPh)] (12112-97-9,47245-62-5,59388-73-7)

Guidance literature:

With carbon monoxide; In acetone; absence of air, in dark; 1 atm CO, 30°C; distn.; kinetics followed by IR spectroscopy; Kinetics;

DOI:10.1039/DT9770000909

Reference yield:

triphenylphosphine-dicarbonyl(1-2-η:3-4-η-1,4-diphenyl-1-azabuta-1,3-diene)iron (12119-27-6,315181-26-1) → tricarbonyl[(1-4-η)-1,4-diphenyl-1-azabuta-1,3-diene]iron (12112-97-9)

Guidance literature:

With carbon monoxide; In toluene; byproducts: PPh3; pressure of CO: 1 atm; temp.: 35-50°C; not separated, determined by i.r. spect.; Kinetics;

DOI:10.1039/DT9800000634

upstream raw materials:

(η2-PhCH=CHCHO)Fe(CO)4

triphenylphosphine-dicarbonyl(1-2-η:3-4-η-1,4-diphenyl-1-azabuta-1,3-diene)iron

triphenylarsine-dicarbonyl(1-2-η:3-4-η-1,4-diphenyl-1-azabuta-1,3-diene)iron

triphenylstibine-dicarbonyl(1-2-η:3-4-η-1,4-diphenyl-1-azabuta-1,3-diene)iron

Downstream raw materials:

{(η4-styrene)CH(C6H5)N(C6H5)ethoxycarbene}iron(carbonyl)2

{(η4-styrene)CH(m-CH3C6H4)N(C6H5)ethoxycarbene}iron(carbonyl)2

{(η4-styrene)CH(p-CF3C6H4)N(C6H5)ethoxycarbene}iron(carbonyl)2

(cyclohexa-1,3-diene)iron tricarbonyl