hexacarbonyl{η4-exo-1-(dicarbonyl(η5-cyclopentadienyl)ferrio)-endo-1-methyl-2.5-diphenylsilole}dicobalt

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Chemical Name:hexacarbonyl{η4-exo-1-(dicarbonyl(η5-cyclopentadienyl)ferrio)-endo-1-methyl-2.5-diphenylsilole}dicobalt
CAS No.:121919-47-9
Molecular Formula:C₃₀H₂₀Co₂FeO₈Si
Molecular Weight:710.403
Hs Code.:

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Chemical Property of hexacarbonyl{η4-exo-1-(dicarbonyl(η5-cyclopentadienyl)ferrio)-endo-1-methyl-2.5-diphenylsilole}dicobalt

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Technology Process of hexacarbonyl{η4-exo-1-(dicarbonyl(η5-cyclopentadienyl)ferrio)-endo-1-methyl-2.5-diphenylsilole}dicobalt

There total 1 articles about hexacarbonyl{η4-exo-1-(dicarbonyl(η5-cyclopentadienyl)ferrio)-endo-1-methyl-2.5-diphenylsilole}dicobalt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 15.0%

: 15226-74-1,61091-28-9,61117-58-6
dicobalt octacarbonyl

: 121919-41-3
dicarbonyl(η5-cyclopentadienyl)(1-methyl-2,5-diphenylsilacyclopentadien-1-yl)iron

: 121919-47-9
hexacarbonyl{η4-exo-1-(dicarbonyl(η5-cyclopentadienyl)ferrio)-endo-1-methyl-2.5-diphenylsilole}dicobalt

Guidance literature:: In hexane; under N2, stirring at room temp., 12 h; cooling to -20 °C (pptn.), filtration, chromy. on acid alumina column (hexane/CH2Cl2, 1/1), collecting the orange band, vac. evapn., crystn. (4x) from toluene/hexane at -20 °C, elem. anal.;

Reference yield: 19.0%

: 121919-47-9
hexacarbonyl{η4-exo-1-(dicarbonyl(η5-cyclopentadienyl)ferrio)-endo-1-methyl-2.5-diphenylsilole}dicobalt

: 639-58-7
triphenyltin chloride

: 13964-91-5,30653-57-7
Ph3SnCo(CO)4

: 121919-51-5
dicarbonyl{η4-exo-1(dicarbonyl(η5-cyclopentadienyl)ferrio)-endo-1-methyl-2,5-diphenylsilole}(triphenylstannyl)cobalt

Guidance literature:: With sodium amalgam; In tetrahydrofuran; byproducts: NaCl, (CO)4CoNa; under N2, stirring a soln. of the tungsten complex in THF with sodium amalgam (1%), 2 h, addn. of Ph3SnCl at - 78 °C, warming to room temp., stirring 12 h; vac. evapn., chromy. on acidic alumina , the red-orange band (CH2Cl2/hexane, 1/1) was collected, vac. evapn., crystn. from hexane at -78°C, elem. anal.;