pallada-2,4-bis(carbomethoxy)-3,5-diphenylcyclopentadiene-bipyridyl

Base Information

• Chemical Name: pallada-2,4-bis(carbomethoxy)-3,5-diphenylcyclopentadiene-bipyridyl
• CAS No.: 886758-94-7
• Molecular Formula: C₃₀H₂₄N₂O₄Pd
• Molecular Weight: 582.952
• Mol file: 886758-94-7.mol

Synonyms:

Chemical Property of pallada-2,4-bis(carbomethoxy)-3,5-diphenylcyclopentadiene-bipyridyl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of pallada-2,4-bis(carbomethoxy)-3,5-diphenylcyclopentadiene-bipyridyl

There total 1 articles about pallada-2,4-bis(carbomethoxy)-3,5-diphenylcyclopentadiene-bipyridyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

[2,2]bipyridinyl (366-18-7) + phenylpropynoic acid methyl ester (4891-38-7) + bis(dibenzylideneacetone)-palladium(0) (32005-36-0) → pallada-2,4-bis(carbomethoxy)-3,5-diphenylcyclopentadiene-bipyridyl (886758-94-7)

Guidance literature:

In tetrahydrofuran; byproducts: Pd; (under N2, Schlenk); suspn. of Pd-complex, 2,2'-bipyridyl stirred at room temp. for 10 min in THF, methyl phenylpropynoate added, 2 h; solvent removed in vacuo, washed with Et2O, dissolved in CH2Cl2, filtered, solvent removed in vacuo; elem. anal.;

DOI:10.1016/j.ica.2005.06.058

upstream raw materials:

[2,2]bipyridinyl

phenylpropynoic acid methyl ester

bis(dibenzylideneacetone)-palladium⁽⁰⁾