Methyl2-deoxy-2-[[(phenylmethoxy)carbonyl]amino]-3-O-(phenylmethyl)-alpha-D-glucopyranoside6-benzoate

Base Information

Chemical Name:Methyl2-deoxy-2-[[(phenylmethoxy)carbonyl]amino]-3-O-(phenylmethyl)-alpha-D-glucopyranoside6-benzoate
CAS No.:87907-36-6
Molecular Formula:C29H31NO8
Molecular Weight:521.567
Hs Code.:
Mol file:87907-36-6.mol

Synonyms:METHYL2-DEOXY-2-[[(PHENYLMETHOXY)CARBONYL]AMINO]-3-O-(PHENYLMETHYL)-ALPHA-D-GLUCOPYRANOSIDE6-BENZOATE;

Suppliers and Price of Methyl2-deoxy-2-[[(phenylmethoxy)carbonyl]amino]-3-O-(phenylmethyl)-alpha-D-glucopyranoside6-benzoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Crysdot
((2R,3S,4R,5R,6S)-4-(Benzyloxy)-5-(((benzyloxy)carbonyl)amino)-3-hydroxy-6-methoxytetrahydro-2H-pyran-2-yl)methylbenzoate 97%
1g
$ 119.00

Crysdot
((2R,3S,4R,5R,6S)-4-(Benzyloxy)-5-(((benzyloxy)carbonyl)amino)-3-hydroxy-6-methoxytetrahydro-2H-pyran-2-yl)methylbenzoate 97%
5g
$ 356.00

Crysdot
((2R,3S,4R,5R,6S)-4-(Benzyloxy)-5-(((benzyloxy)carbonyl)amino)-3-hydroxy-6-methoxytetrahydro-2H-pyran-2-yl)methylbenzoate 97%
10g
$ 584.00

Chemenu
((2R,3S,4R,5R,6S)-4-(benzyloxy)-5-(((benzyloxy)carbonyl)amino)-3-hydroxy-6-methoxytetrahydro-2H-pyran-2-yl)methylbenzoate 97%
10g
$ 552.00

Chemenu
((2R,3S,4R,5R,6S)-4-(benzyloxy)-5-(((benzyloxy)carbonyl)amino)-3-hydroxy-6-methoxytetrahydro-2H-pyran-2-yl)methylbenzoate 97%
5g
$ 337.00

Total 32 raw suppliers

Chemical Property of Methyl2-deoxy-2-[[(phenylmethoxy)carbonyl]amino]-3-O-(phenylmethyl)-alpha-D-glucopyranoside6-benzoate

Chemical Property:

Boiling Point:688.7±55.0 °C(Predicted)
PKA:10.14±0.70(Predicted)
PSA：112.55000
Density:1.29±0.1 g/cm3(Predicted)
LogP:3.84690

Purity/Quality:

98% ^*data from raw suppliers

((2R,3S,4R,5R,6S)-4-(Benzyloxy)-5-(((benzyloxy)carbonyl)amino)-3-hydroxy-6-methoxytetrahydro-2H-pyran-2-yl)methylbenzoate 97% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Methyl2-deoxy-2-[[(phenylmethoxy)carbonyl]amino]-3-O-(phenylmethyl)-alpha-D-glucopyranoside6-benzoate

There total 5 articles about Methyl2-deoxy-2-[[(phenylmethoxy)carbonyl]amino]-3-O-(phenylmethyl)-alpha-D-glucopyranoside6-benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 613-90-1
benzoyl cyanide

: 87907-35-5
methyl 2--3-O-benzyl-2-deoxy-α-D-glucopyranoside

: 87907-36-6
methyl 6-O-benzoyl-3-O-benzyl-2-(benzyloxycarbonyl)amino-2-deoxy-α-D-glucopyranoside

Guidance literature:: With pyridine; In dichloromethane; for 5h; Ambient temperature;
DOI:10.1016/0008-6215(84)85281-7

Reference yield: 56.0%

: 2-azido-3-O-benzyl-6-O-benzoyl-2-deoxy-D-glucopyranoside

: 501-53-1,94274-21-2
benzyl chloroformate

: 603-35-0
triphenylphosphine

: methyl 2-(triphenylphosphoranylidene)amino-3-O-benzyl-6-O-benzoyl-2-deoxy-β-D-glucopyranoside

: 87907-36-6
methyl 6-O-benzoyl-3-O-benzyl-2-(benzyloxycarbonyl)amino-2-deoxy-α-D-glucopyranoside

Guidance literature:: 2-azido-3-O-benzyl-6-O-benzoyl-2-deoxy-D-glucopyranoside; triphenylphosphine; With silica gel; In tetrahydrofuran; water; at 20 ℃; for 3h;

benzyl chloroformate; With sodium hydrogencarbonate; In tetrahydrofuran; water; at 0 ℃; for 3h;
DOI:10.1021/acs.joc.5b02468

Reference yield:

: 100-39-0
benzyl bromide

: 87907-36-6
methyl 6-O-benzoyl-3-O-benzyl-2-(benzyloxycarbonyl)amino-2-deoxy-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: 91 percent / barium oxide, barium hydroxide octahydrate / dimethylformamide / 5 h

2: 89 percent / 60 percent aq. acetic acid / 0.5 h / 100 °C

3: 90 percent / pyridine / CH₂Cl₂ / 5 h / Ambient temperature

With pyridine; barium hydroxide octahydrate; acetic acid; barium(II) oxide; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/0008-6215(84)85281-7