p-(t-BUTYLDIMETHYLSILOXY)STYRENE

Base Information

Chemical Name:p-(t-BUTYLDIMETHYLSILOXY)STYRENE
CAS No.:84494-81-5
Molecular Formula:C14H22OSi
Molecular Weight:234.414
Hs Code.:2931900090
DSSTox Substance ID:DTXSID60451332
Nikkaji Number:J998.736C
Wikidata:Q82271305
Mol file:84494-81-5.mol

Synonyms:4-(tert-butyldimethylsiloxy)styrene;p-(tert-butyldimethylsiloxy)styrene;TBDMS polymer

Suppliers and Price of p-(t-BUTYLDIMETHYLSILOXY)STYRENE

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
PARA-(TERT-BUTYLDIMETHYLSILOXY)STYRENE 95.00%
5MG
$ 505.07

Total 29 raw suppliers

Chemical Property of p-(t-BUTYLDIMETHYLSILOXY)STYRENE

Chemical Property:

Vapor Pressure:0.015mmHg at 25°C
Refractive Index:1.499
Boiling Point:266.033 °C at 760 mmHg
Flash Point:111.258 °C
PSA：9.23000
Density:0.91 g/cm³
LogP:4.71360
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:4
Exact Mass:234.143991855
Heavy Atom Count:16
Complexity:232

Purity/Quality:

97% ^*data from raw suppliers

PARA-(TERT-BUTYLDIMETHYLSILOXY)STYRENE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:
Statements: 36/37/38
Safety Statements: 26-36/37/39

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)(C)[Si](C)(C)OC1=CC=C(C=C1)C=C

Technology Process of p-(t-BUTYLDIMETHYLSILOXY)STYRENE

There total 7 articles about p-(t-BUTYLDIMETHYLSILOXY)STYRENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 18162-48-6
tert-butyldimethylsilyl chloride

: 2628-17-3,24979-70-2
4-Vinylphenol

: 84494-81-5
1-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-4-ethenyl benzene

Guidance literature:: With triethylamine; In dichloromethane; N,N-dimethyl-formamide; at 20 ℃; for 3h;
DOI:10.1021/acs.orglett.6b01825

Reference yield: 70.0%

: tert-butyl(4-ethylphenoxy)-dimethylsilane

: 84494-81-5
1-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-4-ethenyl benzene

Guidance literature:: With 2-chloroanthracene-9,10-dione; cobalt(II) diacetate tetrahydrate; butane-2,3-dione dioxime; In 1,2-dichloro-ethane; at 20 - 30 ℃; for 36h; Irradiation; Schlenk technique; Sealed tube; Inert atmosphere;
DOI:10.1021/jacs.1c05479

Reference yield: 68.0%

: 120743-99-9
p-[(tert-butyldimethylsilyl)oxy]benzaldehyde

: 74-88-4
methyl iodide

: 84494-81-5
1-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-4-ethenyl benzene

Guidance literature:: With 9-(4-trifluoromethyl)phenyl-9-phosphabicyclo[4.2.1]nonane oxide; diphenylsilane; sodium t-butyl carbonate; In toluene; at 140 ℃; for 48h; Inert atmosphere; Schlenk technique; Sealed tube;
DOI:10.1002/anie.201406103