(3aS,8bS)-4-(4-(2,2-diphenylvinyl)phenyl)-1,2,3,3a,4,8b-hexahydrocyclopenta[b]indole

Base Information

Chemical Name:(3aS,8bS)-4-(4-(2,2-diphenylvinyl)phenyl)-1,2,3,3a,4,8b-hexahydrocyclopenta[b]indole
CAS No.:1118752-92-3
Molecular Formula:C31H27N
Molecular Weight:413.562
Hs Code.:
Mol file:1118752-92-3.mol

Synonyms:4-[4-(tert-butoxycarbonyl)piperazino]benzoic acid;4-[4-(tert-butyloxycarbonyl)piperazin-1-yl]-benzoic acid;1-(4-boc-piperazin-1-yl)-benzoic acid;4-(4-(1,1-dimethylethoxycarbonyl)piperazin-1-yl)benzoic acid;4-(4-boc-1-piperazineyl)benzoic acid;4-(4-(tert-butoxycarbonyl)piperazin-1-yl)benzoic acid;4-(N-tert-butoxycarbonyl-4-piperazinyl)benzoic acid;1-(4-carboxyphenyl)-4-Boc piperazine;4-{4-(t-Butoxycarbonyl)piperazin-1-yl}-benzoic Acid;4-(4-Boc-piperazin-1-yl)benzoicacid;4-(4-(1,1-dimethylethoxycarbonyl)-piperazinyl)benzoic acid;1,2,3,3a,4,8b-hexahydro-4-[4-(2,2-diphenylethenyl)phenyl]cyclopent[b]indole;4-(4-carboxyphenyl)piperazine-1-carboxylic acid tert-butyl ester;4-(4-(2,2-diphenylvinyl)phenyl)-1,2,3,3a,4,8b-hexahydrocyclopenta[b]indole;

Suppliers and Price of (3aS,8bS)-4-(4-(2,2-diphenylvinyl)phenyl)-1,2,3,3a,4,8b-hexahydrocyclopenta[b]indole

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of (3aS,8bS)-4-(4-(2,2-diphenylvinyl)phenyl)-1,2,3,3a,4,8b-hexahydrocyclopenta[b]indole

Chemical Property:

PSA：3.24000
LogP:8.12830

Purity/Quality:: >98% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of (3aS,8bS)-4-(4-(2,2-diphenylvinyl)phenyl)-1,2,3,3a,4,8b-hexahydrocyclopenta[b]indole

There total 3 articles about (3aS,8bS)-4-(4-(2,2-diphenylvinyl)phenyl)-1,2,3,3a,4,8b-hexahydrocyclopenta[b]indole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 80278-94-0
1,2,3,3a,4,8b-hexahydrocyclopent[b]indole

: 18648-66-3
1-bromo-4-(2,2-diphenylvinyl)benzene

: 1118752-92-3
1,2,3,3a,4,8b-hexahydro-4-[4-(2,2-diphenylethenyl)phenyl]cyclopent[b]indole

Guidance literature:: With tri-tert-butyl phosphine; potassium tert-butylate; palladium diacetate; In toluene; at 80 ℃;
DOI:10.1021/ol300054a

Reference yield:

: 120-92-3
cyclopentanone

: 1118752-92-3
1,2,3,3a,4,8b-hexahydro-4-[4-(2,2-diphenylethenyl)phenyl]cyclopent[b]indole

Guidance literature:: Multi-step reaction with 3 steps

1: sodium acetate; acetic acid / dichloromethane; water / 2 h / Reflux

2: sodium tetrahydroborate; acetic acid / 20 °C

3: tri-tert-butyl phosphine; potassium tert-butylate; palladium diacetate / 5,5-dimethyl-1,3-cyclohexadiene / 120 °C

With sodium tetrahydroborate; tri-tert-butyl phosphine; potassium tert-butylate; sodium acetate; palladium diacetate; acetic acid; In 5,5-dimethyl-1,3-cyclohexadiene; dichloromethane; water;
DOI:10.1016/j.dyepig.2011.02.009

Reference yield:

: 100-63-0
phenylhydrazine

: 1118752-92-3
1,2,3,3a,4,8b-hexahydro-4-[4-(2,2-diphenylethenyl)phenyl]cyclopent[b]indole

Guidance literature:: Multi-step reaction with 3 steps

1: sodium acetate; acetic acid / dichloromethane; water / 2 h / Reflux

2: sodium tetrahydroborate; acetic acid / 20 °C

3: tri-tert-butyl phosphine; potassium tert-butylate; palladium diacetate / 5,5-dimethyl-1,3-cyclohexadiene / 120 °C

With sodium tetrahydroborate; tri-tert-butyl phosphine; potassium tert-butylate; sodium acetate; palladium diacetate; acetic acid; In 5,5-dimethyl-1,3-cyclohexadiene; dichloromethane; water;
DOI:10.1016/j.dyepig.2011.02.009