bis(triphenylphosphine)gold tricyanomethanide

Base Information

• Chemical Name: bis(triphenylphosphine)gold tricyanomethanide
• CAS No.: 123826-29-9
• Molecular Formula: C₄N₃*C₃₆H₃₀AuP₂
• Molecular Weight: 811.612
• Mol file: 123826-29-9.mol

Synonyms:

Chemical Property of bis(triphenylphosphine)gold tricyanomethanide

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

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Technology Process of bis(triphenylphosphine)gold tricyanomethanide

There total 4 articles about bis(triphenylphosphine)gold tricyanomethanide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

bis(triphenylphosphine)gold(I) chloride (14126-30-8,14586-70-0) + potassium tricyanomethanide (34171-69-2) → bis(triphenylphosphine)gold tricyanomethanide (123826-29-9)

Guidance literature:

In dichloromethane; reactn. of Au-compd. and KTCM in CH2Cl2 overnight; pptn. by addn. of Et2O;

Reference yield: 80.0%

tris[triphenylphosphinegold(I)]oxonium tetrafluoroborate (53317-87-6) + ethenetetracarbonitrile (670-54-2) → gold(I) cyanide (586959-39-9) + bis(triphenylphosphine)gold tricyanomethanide (123826-29-9)

Guidance literature:

In tetrahydrofuran; stirred for 4 h; pptn. isolated, washed with acetone, dried: AuCN (identified as AuCN*PPh3), soln. evapd. to dryness, recrystn. from acetone by pentane: (Au(PPh3)2(C(CN)3); elem. anal.;

DOI:10.1016/0022-328X(89)87238-9

Reference yield: 59.0%

tris[triphenylphosphinegold(I)]oxonium tetrafluoroborate (53317-87-6) + tetracyanoethylene*C12H8(C6H5)2 (123528-41-6) → gold(I) cyanide (586959-39-9) + bis(triphenylphosphine)gold tricyanomethanide (123826-29-9) + 2,4-dihydro-1,3-diphenylcyclopenta(b)indene (33836-49-6)

Guidance literature:

In tetrahydrofuran; stirred for 4 h; pptn. isolated, washed (THF), dried: AuCN, soln. evapd. to dryness, extn. (benzene), evapn. to dryness: 2,4-dihydro-1,3-diphenylcyclopenta(b)indene, after extn. with benzene residue recrystd. (acetone/hexane): (Au(PPh3)2)(C(CN)3);

DOI:10.1016/0022-328X(89)87238-9

upstream raw materials:

tris[triphenylphosphinegold(I)]oxonium tetrafluoroborate

tetracyanoethylene*C₁₂H₈(C₆H₅)2

toluene-tetracyanoethylene charge transfer complex

ethenetetracarbonitrile

Refernces