33836-49-6Relevant academic research and scientific papers
N-Heterocyclic Carbene/Lewis Acid Dual Catalysis for the Divergent Construction of Enantiopure Bridged Lactones and Fused Indenes
Wang, Zhan-Yong,Ding, Ya-Li,Li, Shi-Ning,Cheng, Ying
, p. 11871 - 11881 (2016)
The chiral triazole carbene and Ti(OPr-i)4 cocatalyzed reaction between α,β-unsaturated aldehydes and 2-(aroylvinyl)benzaldehydes was systematically studied. A divergence in reaction pathways was observed under different reaction conditions. In benzene solvent and at ambient temperature, the reaction produced 4,5-dihydro-1,4-methanobenzo[c]oxepin-3-ones, the bridged caprolactones, as the major products in moderate yields with excellent enantioselectivity. The same reaction in dichloroethane and at 50 °C, however, gave 2,8-dihydrocyclopenta[a]indenes as the major products in most cases. The application of the method developed was demonstrated by the transformation of the bridged lactone products into enantiopure 4-hydroxy-1,2,3,4-tetrahydronaphthalene-2-carboxylic acids.
Synthesis and crystal structure of bis(triphenylphosphine)gold tricyanomethanide, +-
Naukova, T. V.,Kravtsov, D. N.,Kuz'mina, L. G.,Dvortsova, N. V.,Poray-Koshits, M. A.,Perevalova, E. G.
, p. 465 - 471 (2007/10/02)
A new unusual transformation of tetracyanoethylene (TCE) into a tricyanomethanide anion - has been found.This transformation occurs as a result of action of tris(triphenylphosphinegold)oxonium tetrafluoroborate +B
