[(η6-benzene)Ru(((2,6-dimethylphenyl)NCMe)2CH)]BPh4

Base Information

• Chemical Name: [(η6-benzene)Ru(((2,6-dimethylphenyl)NCMe)2CH)]BPh4
• CAS No.: 1195949-60-0
• Molecular Formula: C₂₄H₂₀B*C₂₇H₃₁N₂Ru
• Molecular Weight: 803.86
• Mol file: 1195949-60-0.mol

Synonyms:

Chemical Property of [(η6-benzene)Ru(((2,6-dimethylphenyl)NCMe)2CH)]BPh4

Chemical Property:

Purity/Quality:

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Useful:

Technology Process of [(η6-benzene)Ru(((2,6-dimethylphenyl)NCMe)2CH)]BPh4

There total 1 articles about [(η6-benzene)Ru(((2,6-dimethylphenyl)NCMe)2CH)]BPh4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

dichloro(benzene)ruthenium(II) dimer (37366-09-9) + lithium N,N'-bis(2,6-dimethylphenyl)-2,4-pentanediiminate (482323-03-5,604806-75-9) + sodium tetraphenyl borate (143-66-8) → [(η6-benzene)Ru(((2,6-dimethylphenyl)NCMe)2CH)]BPh4 (1195949-60-0)

Guidance literature:

In dichloromethane; byproducts: LiCl, NaCl; (N2); using Schlenk techniques; addn. of Li(N(Me2C6H3)CMe)2CH (2 equiv.)/CH2Cl2 to (C6H6RuCl2)2 for 20 min; stirring for 14 h; filtration, washing; concn., addn. pentane; pptn., decanting; drying; dissolving in CH2Cl2; addn. to NaBPh4; stirring for 1 h; filtration, concn.; addn. of pentane; pptn.; washing several times with n-pentane; drying under vac. overnight;

DOI:10.1021/om900634s

upstream raw materials:

dichloro(benzene)ruthenium(II) dimer

lithium N,N'-bis(2,6-dimethylphenyl)-2,4-pentanediiminate

sodium tetraphenyl borate