[Ag(4-(trimethylammonio)benzenethiolate)2]PF₆

Base Information

• Chemical Name: [Ag(4-(trimethylammonio)benzenethiolate)2]PF₆
• CAS No.: 690957-64-3
• Molecular Formula: C₁₈H₂₆AgN₂S₂*F₆P
• Molecular Weight: 587.382
• Mol file: 690957-64-3.mol

Synonyms:

Chemical Property of [Ag(4-(trimethylammonio)benzenethiolate)2]PF₆

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Ag(4-(trimethylammonio)benzenethiolate)2]PF₆

There total 1 articles about [Ag(4-(trimethylammonio)benzenethiolate)2]PF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

Ag(PPh3)2Cl (82474-94-0) + 4-(trimethylammonio)benzene thiolate hexafluorophosphate → [Ag(4-(trimethylammonio)benzenethiolate)2]PF6 (690957-64-3) + tetrakis(triphenylphosphine)silver hexafluorophosphate (111267-04-0)

Guidance literature:

With Et₃N; In methanol; dichloromethane; byproducts: HNEt3PF6, HnEt3Cl; to a suspn. of a ligand (0.21 mmol) in CH3OH was added Et3N; the soln. was then treated with a soln. of Ag-contg. compd. (0.20 mmol) in CH2Cl2; the mixt. was refluxed on an oil bath for 0.5 h; the ppt. was filtered off and the filtrate was cooled down to 5°C; the solid was redissolved in CH3CN; diethyl ether was allowed to diffuse into the CH3CN soln.; the crystals were washed with CH2Cl2/Et2O (1:4)and dried in vac.; elem. anal.;

DOI:10.1016/j.jorganchem.2004.01.016

Reference yield: 95.0%

[Ag(4-(trimethylammonio)benzenethiolate)2]PF6 (690957-64-3) + potassium dicyanoaurate → ([Ag(4-trimethylammoniobenzenethiol)2][Au(CN)2])2 (911814-55-6)

Guidance literature:

In methanol; N,N-dimethyl-formamide; addn. of a soln. of gold complex in methanol to a soln. of silver complex in DMF; filtration, layering with Et2O, filtration, washing with methanol/Et2O 1:4, drying in vac.; elem. anal.;

DOI:10.1021/ic060655m

Reference yield: 75.0%

sodium sulfide (1313-82-2) + [Ag(4-(trimethylammonio)benzenethiolate)2]PF6 (690957-64-3) + N,N-dimethyl-formamide (68-12-2,33513-42-7) + triphenylphosphine (603-35-0) + acetonitrile (75-05-8,26809-02-9) → ([Ag3(4-(trimethylammonio)benzenethiolate)4](PF6)3*2(N,N-dimethylformamide))n + [Ag14(μ6-S)(4-(trimethylammonio)benzenethiolate)12(PPh3)8](PF6)12*12(acetonitrile)

Guidance literature:

In N,N-dimethyl-formamide; acetonitrile; byproducts: Ag2S, NaPF6, (CH3)3NC6H4S; Na2S (0.05 mmol) was added to the soln. of Ag-contg. compd. (0.8 mmol) in CH3CN/DMF; the ppt. was filtered off; Et2O was allowed to diffuse into the filtrate; standing at ambient temp. for several days; the crystals were sepd. mech.; elem. anal.;

DOI:10.1016/j.jorganchem.2004.01.016

upstream raw materials:

Ag(PPh₃)2Cl

Downstream raw materials:

([Ag(4-trimethylammoniobenzenethiol)2][Au(CN)2])2