1-(naphthalen-1-yl)ethyl acetate

Base Information

• Chemical Name: 1-(naphthalen-1-yl)ethyl acetate
• CAS No.: 16197-94-7
• Molecular Formula: C₁₄H₁₄O₂
• Molecular Weight: 214.264
• Mol file: 16197-94-7.mol

Synonyms:

Chemical Property of 1-(naphthalen-1-yl)ethyl acetate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-(naphthalen-1-yl)ethyl acetate

There total 34 articles about 1-(naphthalen-1-yl)ethyl acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

Isopropenyl acetate (108-22-5) + 1-(1-naphthyl)ethanol (57605-95-5,1517-72-2) → (S)-1-(1-Naphthyl)ethanol (15914-84-8,1517-72-2) + (R)-1-(naphth-1-yl)ethanol (42177-25-3,1517-72-2) + 1-(naphthalen-1-yl)ethyl acetate (16197-95-8,57573-90-7,92697-21-7,16197-94-7)

Guidance literature:

With Candida antarctica lipase B; dicarbonyl(chloro)(η⁵-pentaphenylcyclopentadienyl)ruthenium(II); potassium tert-butylate; sodium carbonate; In tetrahydrofuran; toluene; at 20 ℃; for 24h;

DOI:10.1021/ja051576x

Reference yield: 46.0%

vinyl acetate (108-05-4,9003-20-7) + 1-(1-naphthyl)ethanol (57605-95-5,1517-72-2) → (S)-1-(1-Naphthyl)ethanol (15914-84-8,1517-72-2) + (R)-1-(naphth-1-yl)ethanol (42177-25-3,1517-72-2) + 1-(naphthalen-1-yl)ethyl acetate (16197-95-8,57573-90-7,92697-21-7,16197-94-7)

Guidance literature:

With lipase LIP; In octane; at 30 ℃; for 0.15h; Yields of byproduct given;

DOI:10.1271/bbb.59.271

Reference yield: 45.0%

vinyl acetate (108-05-4,9003-20-7) + 1-(1-naphthyl)ethanol (57605-95-5,1517-72-2) → (S)-1-(1-Naphthyl)ethanol (15914-84-8,1517-72-2) + 1-(naphthalen-1-yl)ethyl acetate (16197-95-8,57573-90-7,92697-21-7,16197-94-7)

Guidance literature:

With Candida antarctica lipase B; In 1,1,1,2-tetrafluoroethane; at 25 ℃; for 72h; optical yield given as %ee; Resolution of racemate; Enzymatic reaction;

DOI:10.1016/j.tetlet.2009.03.037

upstream raw materials:

acetic acid 1-(1-naphthyl)ethyl ester

1-(1-naphthyl)ethanol

acetic anhydride

Isopropenyl acetate

Downstream raw materials:

(R)-1-(naphth-1-yl)ethanol