2,2'-Bis(trifluoromethanesulfonyloxy)-1,1'-biphenyl

Base Information

• Chemical Name: 2,2'-Bis(trifluoromethanesulfonyloxy)-1,1'-biphenyl
• CAS No.: 17763-95-0
• Molecular Formula: C14H8F6O6S2
• Molecular Weight: 450.336
• DSSTox Substance ID: DTXSID401141148
• Nikkaji Number: J638.122G
• Mol file: 17763-95-0.mol

Synonyms:17763-95-0;2,2'-Bis(trifluoromethanesulfonyloxy)-1,1'-biphenyl;Methanesulfonic acid, 1,1,1-trifluoro-, 1,1'-[1,1'-biphenyl]-2,2'-diyl ester;2,2/'-BIS(TRIFLUOROMETHANESULFONYLOXY)-1,1/'-BIPHENYL;[2-[2-(trifluoromethylsulfonyloxy)phenyl]phenyl] trifluoromethanesulfonate;SCHEMBL7023211;VAEJFEYIJHDWKE-UHFFFAOYSA-N;DTXSID401141148;MFCD00799480;2,2-Bis(trifluoromethanesulfonyloxy)-1,1-biphenyl,99%(1,1-biphenolbistriflate);CS-0107510

Chemical Property of 2,2'-Bis(trifluoromethanesulfonyloxy)-1,1'-biphenyl

Chemical Property:

• PSA: 103.50000
• LogP: 5.97200
• XLogP3: 5.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 12
• Rotatable Bond Count: 5
• Exact Mass: 449.96664929
• Heavy Atom Count: 28
• Complexity: 670

Purity/Quality:

99% ^*data from raw suppliers

2,2'-Bis(trifluoromethanesulfonyloxy)-1,1'-biphenyl, 99% (1,1'-Biphenol bistriflate) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C(=C1)C2=CC=CC=C2OS(=O)(=O)C(F)(F)F)OS(=O)(=O)C(F)(F)F

Technology Process of 2,2'-Bis(trifluoromethanesulfonyloxy)-1,1'-biphenyl

There total 2 articles about 2,2'-Bis(trifluoromethanesulfonyloxy)-1,1'-biphenyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

2,2'-dihydroxybiphenyl (1806-29-7) + trifluoromethylsulfonic anhydride (358-23-6) → 2,2'-bis-<<(trifluoromethyl)sulfonyl>oxy>biphenyl (17763-95-0)

Guidance literature:

With pyridine; In dichloromethane; at 0 ℃; Inert atmosphere;

DOI:10.1016/j.tet.2009.09.053

Reference yield:

→ 2,2'-bis-<<(trifluoromethyl)sulfonyl>oxy>biphenyl (17763-95-0)

Guidance literature:

2,2'-Dihydroxybiphenyl, Trifluormethylsulfonylfluorid, NEt3/Py.;

Reference yield: 95.0%

2,2'-bis-<<(trifluoromethyl)sulfonyl>oxy>biphenyl (17763-95-0) + 4-methoxy-aniline (104-94-9) → 9-(4-methoxyphenyl)-9H-carbazole (19264-74-5)

Guidance literature:

With tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; potassium phosphate; 2-(dicyclohexylphosphino)-2'-methylbiphenyl; In toluene; at 100 ℃; for 18h;

DOI:10.1021/jo048472+

upstream raw materials:

2,2'-dihydroxybiphenyl

trifluoromethylsulfonic anhydride

Downstream raw materials:

(+/-)-2-(diphenylphosphinyo)-2'-<<(trifluoromethyl)sulfonyl>oxy>biphenyl

2,2'-bis-[bis-(3,5-dimethyl-phenyl)-phosphinoyl]-biphenyl

[1,1'-biphenyl]-2,2'-diylbis(bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphine oxide)

[1,1'-biphenyl]-2,2'-diylbis(diphenylphosphane oxide)