Diacetato{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dm-segphos]

Base Information

Chemical Name:Diacetato{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dm-segphos]
CAS No.:944450-49-1
Molecular Formula:C₅₀H₅₀O₈P₂Ru
Molecular Weight:941.96
Hs Code.:
Mol file:944450-49-1.mol

Synonyms:DIACETATO{(R)-(+)-5,5'-BIS[DI(3,5-XYLYL)PHOSPHINO]-4,4'-BI-1,3-BENZODIOXOLE}RUTHENIUM(II);(R)-Rutheniumdiacetate-(DM-SEGPHOS);

Suppliers and Price of Diacetato{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dm-segphos]

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
(R)-Rutheniumdiacetate-(DM-SEGPHOS)
100mg
$ 165.00

Strem Chemicals
Diacetato{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dm-segphos(R)]
5g
$ 436.00

Strem Chemicals
Diacetato{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dm-segphos(R)]
1g
$ 190.00

Strem Chemicals
Diacetato{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dm-segphos(R)]
250mg
$ 64.00

Medical Isotopes, Inc.
(R)-Rutheniumdiacetate-(DM-SEGPHOS)
100 mg
$ 650.00

Total 11 raw suppliers

Chemical Property of Diacetato{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dm-segphos]

Chemical Property:

Melting Point:>100°C
PSA：116.70000
LogP:8.28680
Sensitive.:air sensitive

Purity/Quality:

99% ^*data from raw suppliers

(R)-Rutheniumdiacetate-(DM-SEGPHOS) ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Uses Diacetato{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dm-segphos] is a coordination compound used for the direct asymmetric reductive amination. (R)-Rutheniumdiacetate-(DM-SEGPHOS) is a coordination compound used for the direct asymmetric reductive amination.

Technology Process of Diacetato{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dm-segphos]

There total 2 articles about Diacetato{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dm-segphos] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: (S)-5,5 ′-bis[di(3,5-xylyl)phosphino]-4,4 ′-bi-1,3-benzodioxole

: 35796-48-6
[(η6-C6H6)RuCl2]

: 127-09-3
sodium acetate

: 944450-49-1,944450-50-4
Ru(OAc)₂(S)-DM-SegPhos

Guidance literature:: (S)-5,5 ′-bis[di(3,5-xylyl)phosphino]-4,4 ′-bi-1,3-benzodioxole; [(η6-C6H6)RuCl2]; In N,N-dimethyl-formamide; at 100 ℃; for 1.5h; Inert atmosphere; Schlenk technique;

sodium acetate; In methanol; N,N-dimethyl-formamide; for 0.333333h; Inert atmosphere; Schlenk technique;
DOI:10.1002/anie.201809719

Reference yield:

: (S)-5,5 ′-bis[di(3,5-xylyl)phosphino]-4,4 ′-bi-1,3-benzodioxole

: 52462-29-0
[ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂

: 127-09-3
sodium acetate

: 944450-49-1,944450-50-4
Ru(OAc)₂(S)-DM-SegPhos

Guidance literature:: (S)-5,5 ′-bis[di(3,5-xylyl)phosphino]-4,4 ′-bi-1,3-benzodioxole; [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂; In ethanol; toluene; at 45 ℃; for 1h;

sodium acetate; In ethanol; toluene; at 45 ℃; for 3h;