MnCo(CO)8(CNC₆H₄-p-OMe)

Base Information

• Chemical Name: MnCo(CO)8(CNC₆H₄-p-OMe)
• CAS No.: 237056-17-6
• Molecular Formula: C₁₆H₇CoMnNO₉
• Molecular Weight: 471.164
• Mol file: 237056-17-6.mol

Synonyms:

Chemical Property of MnCo(CO)8(CNC₆H₄-p-OMe)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of MnCo(CO)8(CNC₆H₄-p-OMe)

There total 2 articles about MnCo(CO)8(CNC₆H₄-p-OMe) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

sodium tetracarbonyl cobaltate (14878-28-5) + Mn(CO)4(CNC6H4-p-OMe)Br (237056-23-4) → MnCo(CO)8(CNC6H4-p-OMe) (237056-17-6)

Guidance literature:

In diethyl ether; Ar-atmosphere; 1.5 equiv. of Co-complex, stirring at room temp. overnight; solvent removal (vac.), chromy. (Al2O3, pentane); can be rexcrystallized(pentane, -70°C);

DOI:10.1016/S0020-1693(99)00081-X

Reference yield: 25.0%

(CO)5MnCo(CO)4 (35646-82-3) + p-methoxyphenylisonitrile (10349-38-9) → MnCo(CO)8(CNC6H4-p-OMe) (237056-17-6)

Guidance literature:

palladium(II) oxide; In benzene; byproducts: CO; Ar-atmosphere; stoich. amts. of metal carbonyl and isonitrile, 5 mol% catalyst, stirring at room temp. (IR monitoring); solvent removal (vac.), chromy. (Al2O3, pentane); can be recrystallized (pentane, -70°C); elem. anal.;

DOI:10.1016/S0020-1693(99)00081-X

upstream raw materials:

sodium tetracarbonyl cobaltate

Mn(CO)4(CNC₆H₄-p-OMe)Br

(CO)5MnCo(CO)4

p-methoxyphenylisonitrile