trans-dichlorobis(2,2'-bipyridyl)ruthenium(II)

Base Information

• Chemical Name: trans-dichlorobis(2,2'-bipyridyl)ruthenium(II)
• CAS No.: 345911-20-8
• Molecular Formula: C₂₀H₁₆Cl₂N₄Ru
• Molecular Weight: 484.35
• Mol file: 345911-20-8.mol

Synonyms:

Chemical Property of trans-dichlorobis(2,2'-bipyridyl)ruthenium(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-dichlorobis(2,2'-bipyridyl)ruthenium(II)

There total 46 articles about trans-dichlorobis(2,2'-bipyridyl)ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

[2,2]bipyridinyl (366-18-7) + dichloro(1,5-cyclooctadiene)ruthenium(II) → cis-dichlorobis(2,2′-bipyridine)ruthenium(II) (345911-20-8,19542-80-4,158060-65-2,34795-02-3,15746-57-3)

Guidance literature:

In N,N-dimethyl-formamide; other Radiation; a suspn. of Ru-complex and bipyridine-compound in DMF was reacted for 45min under microwave irradiation (microwave set-up; 30 s, 600 W; 45 min, 200 W; 10 min, ventilation); the solvent was immediately removed on the rotary evaporator, the solid was washed with diethyl ether and dried on air;

DOI:10.1016/j.ica.2004.07.007

Reference yield: 90.0%

Ru((C5H4N)2)2Cl2(1+)*Cl(1-)*2H2O = {Ru((C5H4N)2)2Cl2}Cl*2H2O → cis-dichlorobis(2,2′-bipyridine)ruthenium(II) (345911-20-8,19542-80-4,158060-65-2,34795-02-3,15746-57-3)

Guidance literature:

With SnCl₂*2HCl; In hydrogenchloride; SnCl2*2HCl added to a soln. of Ru-compd. in HCl; concd. by warming, washed with H2O, air dried;

DOI:10.1016/S0020-1693(00)85316-5

Reference yield: 78.0%

4,4'-bipyridine (553-26-4) + ruthenium(III) chloride trihydrate + lithium chloride → cis-dichlorobis(2,2′-bipyridine)ruthenium(II) (345911-20-8,19542-80-4,158060-65-2,34795-02-3,15746-57-3)

Guidance literature:

In N,N-dimethyl-formamide; for 8h; Reflux; Darkness;

DOI:10.1016/j.jinorgbio.2020.111132

upstream raw materials:

[2,2]bipyridinyl

ruthenium trichloride hydrate

ruthenium(III)chloride

ruthenium(III) chloride hydrate

Downstream raw materials:

{RuCl(py)(bpy)2}⁽¹⁺⁾

chloride

[2,2]bipyridinyl

{Ru(2,2'-bipyridine)2(2-(m-tolylazo)pyridine)}(ClO₄)2*H₂O

Refernces

• 1、 Motimani, Nozuko M.,Ngubane, Siyabonga,Smith, Gregory S.. "Polynuclear heteroleptic ruthenium(II) photoredox catalysts: Evaluation in blue-light-mediated, regioselective thiol-ene reactions". . . Retrieved 2021/12/17.
• 2、 -. "Preparation method of ruthenium-based photosensitizer and application of ruthenium-based photosensitizer in photodynamic therapy of breast cancer". Paragraph 0033-0034; 0036; 0039-0040; 0042; 0044-0045; 0047. . Retrieved 2021/09/01.