TiCl₃(3-tBu-2-OC₆H₃CHNC₆F₅)(tetrahydrofuran)

Base Information

Chemical Name:TiCl₃(3-tBu-2-OC₆H₃CHNC₆F₅)(tetrahydrofuran)
CAS No.:848616-68-2
Molecular Formula:C₂₁H₂₁Cl₃F₅NO₂Ti
Molecular Weight:568.634
Hs Code.:

TiCl<sub>3</sub>(3-tBu-2-OC<sub>6</sub>H<sub>3</sub>CHNC<sub>6</sub>F<sub>5</sub>)(tetrahydrofuran)

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of TiCl₃(3-tBu-2-OC₆H₃CHNC₆F₅)(tetrahydrofuran)

Chemical Property:

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Technology Process of TiCl₃(3-tBu-2-OC₆H₃CHNC₆F₅)(tetrahydrofuran)

There total 1 articles about TiCl₃(3-tBu-2-OC₆H₃CHNC₆F₅)(tetrahydrofuran) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 109-99-9,24979-97-3,77392-70-2
tetrahydrofuran

: 352033-68-2
N-(3-tert-butyl-2-hydroxy)benzylidenepentafluorophenylamine

: 7550-45-0
titanium tetrachloride

: 848616-68-2
TiCl₃(3-tBu-2-OC₆H₃CHNC₆F₅)(tetrahydrofuran)

Guidance literature:: With C₄H₉Li; (CH₃)3SiCl; In tetrahydrofuran; hexane; toluene; (Ar); addn. of n-BuLi in hexane to salicylimine deriv. in THF at -78°C for 5 min, stirring for 4 h at room temp., addn. silane deriv., stirring for 18 h, concg., filtration, addn. to TiCl4 in toluene at 0°C, stirring for 12 h at room temp.; evapn. in vac., recrystn. (CH2Cl2/hexane);
DOI:10.1039/c0dt01225d

Reference yield: 63.0%

: 848616-68-2
TiCl₃(3-tBu-2-OC₆H₃CHNC₆F₅)(tetrahydrofuran)

: TiCl₂(3-tBu-2-OC₆H₃CHNC₆F₅)(p-PhC₆H₄COCHC(CF₃)NPh)

Guidance literature:: In dichloromethane; byproducts: KCl; (Ar); addn. of ketoiminate deriv. to CH2Cl2 soln. of titanium compd. at -78°C, slow warming to room temp., stirring for 20 h; filtration, concg., recrystn. (CH2Cl2/hexane) at room temp., elem. anal.;
DOI:10.1039/c0dt01225d

Reference yield: 58.0%

: 848616-68-2
TiCl₃(3-tBu-2-OC₆H₃CHNC₆F₅)(tetrahydrofuran)

: o-PhC₆H₄C(OK)CHC(CF₃)NPh

: TiCl₂(3-tBu-2-OC₆H₃CHNC₆F₅)(o-PhC₆H₄COCHC(CF₃)NPh)

Guidance literature:: In dichloromethane; byproducts: KCl; (Ar); addn. of ketoiminate deriv. to CH2Cl2 soln. of titanium compd. at -78°C, slow warming to room temp., stirring for 20 h; filtration, concg., recrystn. (CH2Cl2/hexane) at room temp., elem. anal.;
DOI:10.1039/c0dt01225d