methyl trans-8-methoxy-4-cyclooctenecarboxylate

Base Information

• Chemical Name: methyl trans-8-methoxy-4-cyclooctenecarboxylate
• CAS No.: 35193-35-2
• Molecular Formula: C₁₁H₁₈O₃
• Molecular Weight: 198.262
• Mol file: 35193-35-2.mol

Synonyms:

Chemical Property of methyl trans-8-methoxy-4-cyclooctenecarboxylate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl trans-8-methoxy-4-cyclooctenecarboxylate

There total 1 articles about methyl trans-8-methoxy-4-cyclooctenecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,5-cis,cis-cyclooctadiene (1552-12-1,111-78-4) + carbon monoxide (201230-82-2) → Methyl formate (107-31-3) + (Z)-cyclooct-4-ene-1-carboxylic acid methyl ester (16031-48-4) + cis-cyclooct-4-enone (31598-70-6) + 2,5-cyclooctadienyl methyl ester (120983-43-9) + methyl trans-8-methoxy-4-cyclooctenecarboxylate (5230-94-4,35193-34-1,35193-35-2,59367-08-7) + 2-carbomethoxybicyclo<3.3.1>nonan-9-one

Guidance literature:

With sodium acetate; copper dichloride; palladium dichloride; In dichloromethane; at 100 ℃; for 24h; under 3127.8 Torr; Product distribution; Mechanism; other Pd(II)-catalysts, other oxidants, var. conditions;

DOI:10.1135/cccc19922374

Reference yield:

methyl trans-8-methoxy-4-cyclooctenecarboxylate (5230-94-4,35193-34-1,35193-35-2,59367-08-7) → Toluene-4-sulfonic acid (1S,2R)-2-methoxy-cyclooctylmethyl ester

Guidance literature:

Multi-step reaction with 3 steps

1: H₂ / PtO₂

2: LiAlH₄

3: Py

With pyridine; lithium aluminium tetrahydride; hydrogen; platinum(IV) oxide;

DOI:10.1021/ja00757a027

upstream raw materials:

1,5-cis,cis-cyclooctadiene

carbon monoxide