platinum(II) dibenzyldithiocarbamate

Base Information

• Chemical Name: platinum(II) dibenzyldithiocarbamate
• CAS No.: 71391-53-2
• Molecular Formula: C₃₀H₂₈N₂PtS₄
• Molecular Weight: 739.91
• Mol file: 71391-53-2.mol

Synonyms:

Chemical Property of platinum(II) dibenzyldithiocarbamate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of platinum(II) dibenzyldithiocarbamate

There total 1 articles about platinum(II) dibenzyldithiocarbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

sodium dibenzyldithiocarbamate (55310-46-8) + platinum(II) chloride (10025-65-7) → platinum(II) dibenzyldithiocarbamate (71391-53-2)

Guidance literature:

In acetonitrile; byproducts: NaCl; 2 equiv. Na(dbtc) and 1 equiv. PtCl2 in MeCN was heated at 50°C for 4 h; react. mixt. was cooled, ppt. was dissolved in hot chlorobenzene and filtered, solvent was removed to dryness in vacuo; elem. anal.;

DOI:10.1021/ic051261i

Reference yield:

platinum(II) dibenzyldithiocarbamate (71391-53-2) + fullerene-C60 (99685-96-8,161105-99-3,161106-00-9,111138-12-6,133318-63-5,134053-11-5,134931-35-4,134931-36-5,139703-76-7,145633-27-8,175414-73-0,175414-74-1,175414-75-2,175519-12-7,175519-13-8,175519-14-9,175519-15-0,136376-46-0,144906-37-6,144906-38-7,151767-00-9,152882-97-8,152882-98-9,152882-99-0,153062-34-1,154171-74-1,154171-75-2,154333-99-0,154334-00-6,154397-63-4,154460-59-0,199456-56-9,108739-25-9,120329-57-9,120329-58-0) + chlorobenzene (108-90-7) → Pt(dibenzyldithiocarbamate)2*C60*0.5(C6H5Cl)

Guidance literature:

With Cp₂Fe; In benzonitrile; chlorobenzene; slow evapn. soln. Pt(dbdtc)2, Cp2Fe and C60 in PhCl-PhCN (12:1) for 1 week; crystals were washed with MeCN; elem. anal.;

DOI:10.1021/ic051261i

upstream raw materials:

sodium dibenzyldithiocarbamate

platinum(II) chloride

Refernces