piperidino-hexose-reductone

Base Information

• Chemical Name: piperidino-hexose-reductone
• CAS No.: 39994-32-6
• Molecular Formula: C₁₁H₁₇NO₃
• Molecular Weight: 211.261
• Mol file: 39994-32-6.mol

Synonyms:

Chemical Property of piperidino-hexose-reductone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of piperidino-hexose-reductone

There total 8 articles about piperidino-hexose-reductone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

piperidine (110-89-4) + D-glucose (50-99-7) → piperidino-hexose-reductone (34421-11-9,39994-32-6) + 2,3-dihydro-3,5-dihydroxy-6-methyl-4H-pyran-4-one

Guidance literature:

piperidine; D-glucose; In ethanol; for 1.5h; Reflux;

With acetic acid; In ethanol; at 75 ℃; for 32h;

DOI:10.1016/j.foodchem.2021.130052

Reference yield: 20.0%

piperidine (110-89-4) + 1-deoxy-D-erythro-2,3-hexodiulose → 4-hydroxy-2-(hydroxymethyl)-5-methyl-3(2H)-furanone (17678-20-5) + 2,3-dihydro-3,5-dihydroxy-6-methyl-4H-pyran-4-one (28564-83-2) + piperidino-hexose-reductone (34421-11-9,39994-32-6)

Guidance literature:

In ethanol; water; acetic acid; at 75 ℃; for 20h; Heating;

DOI:10.1016/0008-6215(83)88110-5

Reference yield: 20.0%

N-(1-deoxy-D-fructos-1-yl)piperidine (54917-61-2) → piperidino-hexose-reductone (34421-11-9,39994-32-6)

Guidance literature:

With acetic acid; In ethanol; for 20h; Heating;

DOI:10.1021/jf980512l

upstream raw materials:

N-(1-deoxy-D-fructos-1-yl)piperidine

piperidine

N-(1-deoxy-D-fructos-1-yl)piperidine

D-glucose

Downstream raw materials:

2-hydroxy-5-methylene-3-piperidino-cyclopent-2-enone

2-hydroxy-5-methyl-3-piperidino-cyclopent-2-enone