pentacarbonyl(p-methoxythiobenzaldehyde)molybdenum

Base Information

• Chemical Name: pentacarbonyl(p-methoxythiobenzaldehyde)molybdenum
• CAS No.: 128714-20-5
• Molecular Formula: C₁₃H₈MoO₆S
• Molecular Weight: 388.209
• Mol file: 128714-20-5.mol

Synonyms:

Chemical Property of pentacarbonyl(p-methoxythiobenzaldehyde)molybdenum

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of pentacarbonyl(p-methoxythiobenzaldehyde)molybdenum

There total 1 articles about pentacarbonyl(p-methoxythiobenzaldehyde)molybdenum which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

p-methoxy-benzylidene(pentacarbonyl)molybdenum + potassium thioacyanate (333-20-0) → pentacarbonyl(p-methoxythiobenzaldehyde)molybdenum (128714-20-5)

Guidance literature:

With triphenylphosphine; In dichloromethane; acetone; pentane; addn. of KSCN in acetone (room temp.), to a cooled soln. of Mo-compd. in CH2Cl2/pentane (-110°C) under vigorous stirring (change of color from red to violet, under N2); filtn. (silica gel), reducing of volume in high-vac., chromy. on silica gel at -20°C (petroleum ether/CH2Cl2), recrystn. from pentane, elem. anal., mixt. of E/Z isomers (monitored by IR);

DOI:10.1016/0022-328X(90)85006-K

upstream raw materials:

potassium thioacyanate