[ReH₄(PPh₃)₃(NCMe)]PF₆

Base Information

• Chemical Name: [ReH₄(PPh₃)₃(NCMe)]PF₆
• CAS No.: 108571-96-6
• Molecular Formula: C₅₆H₅₂NP₃Re*F₆P
• Molecular Weight: 1163.13

Synonyms:

Chemical Property of [ReH₄(PPh₃)₃(NCMe)]PF₆

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [ReH₄(PPh₃)₃(NCMe)]PF₆

There total 3 articles about [ReH₄(PPh₃)₃(NCMe)]PF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

pentahydridotris(triphenylphosphane)Re(V) (12104-75-5,122169-15-7) + tropylium hexafluorophosphate (29663-54-5) + acetonitrile (75-05-8,26809-02-9) → [ReH4(PPh3)3(NCMe)]PF6 (108571-96-6)

Guidance literature:

In acetonitrile; Mixt. of reagents was stirred for 30 min under N2 atm.;; The mixt. was filtered into Et2O, pentane was added, ppt. was filtered off, washed with Et2O; elem. anal.;;

DOI:10.1039/DT9870000715

Reference yield: 64.0%

potassium hexafluorophosphate (17084-13-8) + pentahydridotris(triphenylphosphane)Re(V) (12104-75-5,122169-15-7) + acetonitrile (75-05-8,26809-02-9) → [ReH4(PPh3)3(NCMe)]PF6 (108571-96-6)

Guidance literature:

With HBF₆*Et₂O; In acetonitrile; byproducts: H2; A suspn. of complex in a soln. of KPF6 in CH3CN was treated with HBF4*Et2O, the mixt. was stirred for 5 min ( N2 atm.);; Et2O and pentane were added, ppt. was recrystd. from CH2Cl2-Et2O-pentane;;

DOI:10.1039/DT9870000715

Reference yield: 62.0%

potassium hexafluorophosphate (17084-13-8) + ReH6(P(C6H5)3)3(1+)*BF4(1-)*3H2O + acetonitrile (75-05-8,26809-02-9) → [ReH4(PPh3)3(NCMe)]PF6 (108571-96-6)

Guidance literature:

In acetonitrile; byproducts: H2; CH3CN was added to a mixt. of complex and KPF6 (N2 atm.);; Et2O and pentane were added, ppt. was recrystd. from CH2Cl2-Et2O-pentane;;

DOI:10.1039/DT9870000715

upstream raw materials:

potassium hexafluorophosphate

acetonitrile

pentahydridotris(triphenylphosphane)Re(V)

tropylium hexafluorophosphate

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 108571-96-6 [ReH₄(PPh₃)₃(NCMe)]PF₆

Send

Send

Metric Ton KG G Pound L ML

Send

Send