Stannane, dibromobis(phenylmethyl)-

Base Information

• Chemical Name: Stannane, dibromobis(phenylmethyl)-
• CAS No.: 10113-32-3
• Molecular Formula: C14H14Br2Sn
• Molecular Weight: 460.783
• Mol file: 10113-32-3.mol

Synonyms:

Chemical Property of Stannane, dibromobis(phenylmethyl)-

Chemical Property:

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Stannane, dibromobis(phenylmethyl)-

There total 2 articles about Stannane, dibromobis(phenylmethyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

tin (7440-31-5) + benzyl bromide (100-39-0) → dibenzyldibromotin(IV) (10113-32-3)

Guidance literature:

In water; toluene; mixt. of tin, H2O and toluene was refluxed with stirring; benzyl bromidewas added slowly with syringe; mixt. was refluxed for 3 h; cooled; filtered; residue dissolved in acetone; filtered; filtrate evapd.; recrystd. (EtOAc);

DOI:10.1016/S0022-328X(01)01398-5

Reference yield:

→ dibenzyldibromotin(IV) (10113-32-3)

Guidance literature:

With acetone;

Reference yield: 99.0%

1H,1H,2H,2H-perfluoro-n-hexyl bromide (38436-14-5) + dibenzyldibromotin(IV) (10113-32-3) → (C4F9C2H4)2Sn(CH2C6H5)2 (444809-28-3)

Guidance literature:

With Mg; In tetrahydrofuran; diethyl ether; (Ar); C4F9C2H4Br in Et2O was added dropwise to stirred suspn. of Mg in Et2O at 0°C; mixt. was stirred at room temp. for 3 h; dild. with Et2O; (C6H5CH2)2SnBr2 in THF was added at 0°C; mixt. was stirred at room temp. for 24 h; dild. with C6H14; filtered through celite pad; filtrate evapd.; residue chromd. (SiO2, C6H14);

DOI:10.1016/S0022-328X(01)01398-5

upstream raw materials:

tin

benzyl bromide

Downstream raw materials:

tetrabenzyltin

(C₄F₉C₂H₄)2Sn(CH₂C₆H₅)2

tribenzyltin bromide