1,2-dihydro-61-ethoxycarbonyl-61-[4'-[(dimethylamino)methyl]-3'-[iodo(triphenylphosphine)platino]benzyloxycarbonyl]-1,2-methano[60]fullerene

Base Information

• Chemical Name: 1,2-dihydro-61-ethoxycarbonyl-61-[4'-[(dimethylamino)methyl]-3'-[iodo(triphenylphosphine)platino]benzyloxycarbonyl]-1,2-methano[60]fullerene
• CAS No.: 399042-73-0
• Molecular Formula: C₉₃H₃₃INO₄PPt
• Molecular Weight: 1581.25
• Mol file: 399042-73-0.mol

Synonyms:

Chemical Property of 1,2-dihydro-61-ethoxycarbonyl-61-[4'-[(dimethylamino)methyl]-3'-[iodo(triphenylphosphine)platino]benzyloxycarbonyl]-1,2-methano[60]fullerene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,2-dihydro-61-ethoxycarbonyl-61-[4'-[(dimethylamino)methyl]-3'-[iodo(triphenylphosphine)platino]benzyloxycarbonyl]-1,2-methano[60]fullerene

There total 1 articles about 1,2-dihydro-61-ethoxycarbonyl-61-[4'-[(dimethylamino)methyl]-3'-[iodo(triphenylphosphine)platino]benzyloxycarbonyl]-1,2-methano[60]fullerene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 37.0%

1-(4'-[(dimethylamino)methyl]-3'-[iodo(triphenylphosphine)platino]benzyl)-3-ethylmalonate (399042-68-3) + iodine (7553-56-2,12190-71-5,8031-47-8) + fullerene-C60 (99685-96-8,161105-99-3,161106-00-9,111138-12-6,133318-63-5,134053-11-5,134931-35-4,134931-36-5,139703-76-7,145633-27-8,175414-73-0,175414-74-1,175414-75-2,175519-12-7,175519-13-8,175519-14-9,175519-15-0,136376-46-0,144906-37-6,144906-38-7,151767-00-9,152882-97-8,152882-98-9,152882-99-0,153062-34-1,154171-74-1,154171-75-2,154333-99-0,154334-00-6,154397-63-4,154460-59-0,199456-56-9,108739-25-9,120329-57-9,120329-58-0) → 1,2-dihydro-61-ethoxycarbonyl-61-[4'-[(dimethylamino)methyl]-3'-[iodo(triphenylphosphine)platino]benzyloxycarbonyl]-1,2-methano[60]fullerene (399042-73-0)

Guidance literature:

With 1,8-diazabicyclo[5.4.0]undec-7-ene; In toluene; the mixt. in toluene was stirred for 17 h under N2; chromd. on silica gel with toluene-methanol, evapd., washed with acetone, dried in vac.; elem. anal.;

DOI:10.1021/om010500g

upstream raw materials:

1-(4'-[(dimethylamino)methyl]-3'-[iodo(triphenylphosphine)platino]benzyl)-3-ethylmalonate

iodine

fullerene-C₆₀