bis[η5-(2-phenylindenyl)]titanium dichloride

Base Information

• Chemical Name: bis[η5-(2-phenylindenyl)]titanium dichloride
• CAS No.: 420134-32-3
• Molecular Formula: C₃₀H₂₂Cl₂Ti
• Molecular Weight: 501.291
• Mol file: 420134-32-3.mol

Synonyms:

Chemical Property of bis[η5-(2-phenylindenyl)]titanium dichloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis[η5-(2-phenylindenyl)]titanium dichloride

There total 1 articles about bis[η5-(2-phenylindenyl)]titanium dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-phenylindene (4505-48-0) + titanium tetrachloride (7550-45-0) → bis[η5-(2-phenylindenyl)]titanium dichloride (420134-32-3)

Guidance literature:

With n-butyllithium; chloro-trimethyl-silane; ammonium chloride; In tetrahydrofuran; diethyl ether; dichloromethane; Ar; nBuLi, 2-Ph-indene, Et2O, -10°C; stirring, room temp.; ppt. dissolved in THF; Me3SiCl in THF added; stirring, room temp., 6 h; aq. NH4Cl added, 0°C; extd. with Et2O; evapn.; dissolved in CH2Cl2; TiCl4/CH2Cl2 added, stirring; solvent removed under vac., residue washed with petroleum ether, dried; elem. anal.;

DOI:10.1039/b315482c

upstream raw materials:

2-phenylindene

titanium tetrachloride