Methyl dihydrosterculate

Base Information

• Chemical Name: Methyl dihydrosterculate
• CAS No.: 10152-62-2
• Molecular Formula: C20H38O2
• Molecular Weight: 310.51500
• Hs Code.: 2916209090
• Mol file: 10152-62-2.mol

Synonyms:(+-)-8-(cis-2-octyl-cyclopropyl)-octanoic acid methyl ester;(+-)-8-(cis-2-Octyl-cyclopropyl)-octansaeure-methylester;Cyclopropaneoctanoic acid,2-octyl-,methyl ester;cis-9,10-methyleneoctadecanoic acid mthyl ester;(+-)-Methyl-cis-9,10-methylenoctadecanoat;Methyl dihydrosterculate;Cyclopropaneoctanoic acid,2-octyl-,methyl ester,trans;cis-9,10-Methylen-octadecansaeure-methylester;Cyclopropaneoctanoic acid,2-octyl-,methyl ester,cis;

Chemical Property of Methyl dihydrosterculate

Chemical Property:

• PSA: 26.30000
• LogP: 6.27680

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Methyl dihydrosterculate

There total 15 articles about Methyl dihydrosterculate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

diiodomethane (75-11-6) + Methyl oleate (112-62-9) → 9,10-Methylen-octadecansaeure-methylester (10152-62-2)

Guidance literature:

Methyl oleate; With diethylzinc; In hexane; dichloromethane; at -5 - 0 ℃; for 1h; Inert atmosphere;

diiodomethane; In hexane; dichloromethane; at 20 ℃; Inert atmosphere;

DOI:10.1016/j.ejmech.2015.12.048

Reference yield: 100.0%

methanol (67-56-1) + 8-((cis)-2-octylcyclopropyl)octanoic acid (4675-61-0) → cis-9,10-Methylen-octadecansaeure-methylester (3971-54-8,5135-07-9,10152-62-2,79795-84-9)

Guidance literature:

With hydrogenchloride; In water; toluene; at 45 ℃; for 14h;

DOI:10.1194/jlr.D001065

Reference yield: 96.0%

diiodomethane (75-11-6) + Methyl oleate (112-62-9) → cis-9,10-Methylen-octadecansaeure-methylester (3971-54-8,5135-07-9,10152-62-2,79795-84-9)

Guidance literature:

diiodomethane; With 2,4,6-Cl₃C₆H₂OZnEt; In dichloromethane; at -40 ℃;

Methyl oleate; In dichloromethane; at 20 ℃;

DOI:10.1002/1521-3773(20001215)39:24<4539::AID-ANIE4539>3.0.CO;2-9

upstream raw materials:

Methyl oleate

octadec-9-enoic acid methyl ester

bis(iodomethyl)zinc

cis-Octadecenoic acid

Downstream raw materials:

8-((cis)-2-octylcyclopropyl)octanoic acid

Refernces

• 1、 Ichihara, Ken'Ichi,Fukubayashi, Yumeto. "Preparation of fatty acid methyl esters for gas-liquid chromatography". . p. 635 - 640. Retrieved 2010.
• 2、 Buist, Peter H.,Findlay, Judy M.. "FLUORINE SUBSTITUENT EFFECTS ON BIO-METHYLENATION OF OLEFINIC FATTY ACIDS". . p. 1433 - 1436. Retrieved 1984.
• 3、 Hofmann,Yoho. "-". . p. 3356. Retrieved 1959.
• 4、 Miyano,Hashimoto. "". . p. 892,897. Retrieved 1973.
• 5、 Kwan, Man-Lung,Mirjafari, Arsalan,McCabe, John R.,O'Brien, Richard A.,Essi IV, David F.,Baum, Leah,West, Kevin N.,Davis, James H.. "Synthesis and thermophysical properties of ionic liquids: Cyclopropyl moieties versus olefins as Tm-reducing elements in lipid-inspired ionic liquids". . p. 12 - 14. Retrieved 2013/02/22.