Gold, tribromo(triethylphosphine)-, (SP-4-2)-

Base Information

• Chemical Name: Gold, tribromo(triethylphosphine)-, (SP-4-2)-
• CAS No.: 56213-25-3
• Molecular Formula: C₆H₁₅AuBr₃P
• Molecular Weight: 554.837
• DSSTox Substance ID: DTXSID50971615
• Mol file: 56213-25-3.mol

Synonyms:56213-25-3;Gold, tribromo(triethylphosphine)-, (SP-4-2)-;DTXSID50971615;Gold(3+) bromide--hexylphosphane (1/3/1)

Chemical Property of Gold, tribromo(triethylphosphine)-, (SP-4-2)-

Chemical Property:

• Vapor Pressure: 7.73mmHg at 25°C
• Boiling Point: 140.2°C at 760 mmHg
• Flash Point: 38.6°C
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 4
• Exact Mass: 553.81067
• Heavy Atom Count: 11
• Complexity: 27.4

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCP.[Br-].[Br-].[Br-].[Au+3]

Technology Process of Gold, tribromo(triethylphosphine)-, (SP-4-2)-

There total 4 articles about Gold, tribromo(triethylphosphine)-, (SP-4-2)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(triethylphosphine)chlorogold(I) (15529-90-5) → (triethylphosphine)gold(I) bromide (14243-60-8) + tribromo(triethylphosphine)gold(III) (56213-25-3) + [((C2H5)3P)AuBr2(C8H4O2N)] (97905-44-7)

Guidance literature:

Multi-step reaction with 3 steps

1: water; ethanol

2: Br₂ / chloroform

3: neat (no solvent)

With Br₂; In ethanol; chloroform; water;

DOI:10.1021/ic00215a026

Reference yield:

(phthalimido)(triethylphosphine)gold(I) (97825-49-5) → (triethylphosphine)gold(I) bromide (14243-60-8) + tribromo(triethylphosphine)gold(III) (56213-25-3) + [((C2H5)3P)AuBr2(C8H4O2N)] (97905-44-7)

Guidance literature:

Multi-step reaction with 2 steps

1: Br₂ / chloroform

2: neat (no solvent)

With Br₂; In chloroform;

DOI:10.1021/ic00215a026

Reference yield:

(phthalimido-(15)N)(triethylphosphine)gold(I) (97825-56-4) → (triethylphosphine)gold(I) bromide (14243-60-8) + tribromo(triethylphosphine)gold(III) (56213-25-3) + [((C2H5)3P)AuBr(C8H4O2(15)N)2] + [((C2H5)3P)AuBr2(C8H4O2(15)N)] + [((C2H5)3P)AuBr2(C8H4O2(15)N)]

Guidance literature:

With Br₂; In chloroform; slight excess of Br2;; not isolated, detected by (31)P-NMR spectroscopy;;

DOI:10.1021/ic00215a026

upstream raw materials:

(phthalimido-⁽¹⁵⁾N)(triethylphosphine)gold(I)

(triethylphosphine)chlorogold(I)

(phthalimido)(triethylphosphine)gold(I)

Downstream raw materials:

(triethylphosphine)gold(I) bromide

Refernces