[Ir(1,5-cyclooctadiene)(NCCH₃)₂]BF₄

Base Information

• Chemical Name: [Ir(1,5-cyclooctadiene)(NCCH₃)₂]BF₄
• CAS No.: 32679-03-1
• Molecular Formula: BF₄*C₁₂H₁₈IrN₂
• Molecular Weight: 469.313
• Mol file: 32679-03-1.mol

Synonyms:

Chemical Property of [Ir(1,5-cyclooctadiene)(NCCH₃)₂]BF₄

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Bis(acetonitrile)(1,5-cyclooctadiene)iridium(I) tetrafluoroborate, min. 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Ir(1,5-cyclooctadiene)(NCCH₃)₂]BF₄

There total 6 articles about [Ir(1,5-cyclooctadiene)(NCCH₃)₂]BF₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.8%

silver tetrafluoroborate (14104-20-2) + bis(1,5-cyclooctadiene)diiridium(I) dichloride (12112-67-3) + acetonitrile (75-05-8,26809-02-9) → 1,5-cyclooctadienebis(acetonitrile)iridium(I) tetrfluoroborate (32679-03-1)

Guidance literature:

bis(1,5-cyclooctadiene)diiridium(I) dichloride; In dichloromethane; for 0.0833333h; Inert atmosphere; Glovebox;

acetonitrile; In dichloromethane; for 0.0833333h; Inert atmosphere; Glovebox;

silver tetrafluoroborate; In dichloromethane; for 0.166667h; Inert atmosphere; Glovebox;

DOI:10.1021/acs.inorgchem.1c00941

Reference yield:

[(1,5-cyclooctadiene)Ir(η6-benzene)]BF4 (74238-34-9) + acetonitrile (75-05-8,26809-02-9) → [Ir(1,5-cyclooctadiene)(NCCH3)2]BF4 (32679-03-1)

Guidance literature:

In acetone; at 24°C for 60 h;

Reference yield:

bis(1,5-cyclooctadiene)diiridium(I) dichloride (12112-67-3) + acetonitrile (75-05-8,26809-02-9) → 1,5-cyclooctadienebis(acetonitrile)iridium(I) tetrfluoroborate (32679-03-1)

Guidance literature:

With thallium(I) tetrafluoroborate; for 0.5h; Inert atmosphere; Schlenk technique;

DOI:10.1021/om300506v

upstream raw materials:

bis(1,5-cyclooctadiene)diiridium(I) dichloride

acetonitrile

silver tetrafluoroborate

sodium tetrafluoroborate

Downstream raw materials:

[(Ir(cod))2(μ-Cl)(μ-1-benzyl-2-imidazolyldiphenylphosphine)]BF4

cis-[Ir(cod)((diphenylphosphanyl)methanol)2]BF₄

iridium(I)(COD)bis(η1-2-phenyl-1,8-naphthyridine)(BF4)

Ir(1,5-cyclooctadiene)(tri(p-tolyl)phosphine)2BF₄