(η5-pentamethylcyclopentadienyl)Zr(C6F5)F

Base Information

Chemical Name:(η5-pentamethylcyclopentadienyl)Zr(C6F5)F
CAS No.:494800-76-9
Molecular Formula:C₂₆H₃₀F₆Zr
Molecular Weight:547.739
Hs Code.:

Synonyms:

Suppliers and Price of (η5-pentamethylcyclopentadienyl)Zr(C6F5)F

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (η5-pentamethylcyclopentadienyl)Zr(C6F5)F

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (η5-pentamethylcyclopentadienyl)Zr(C6F5)F

There total 3 articles about (η5-pentamethylcyclopentadienyl)Zr(C6F5)F which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

: 301195-57-3
(η5-pentamethylcyclopentadienyl)Zr(C6F5)H

: 7664-39-3,12381-92-9,32057-09-3,74835-82-8
hydrogen fluoride

: 494800-76-9
(η5-pentamethylcyclopentadienyl)Zr(C6F5)F

Guidance literature:: In pyridine; pentane; byproducts: H2; under N2; in polyethylene vial; Zr complex dissolved in pentane; four drops of HF-pyridine (70:30) added with stirring; transferred to glass vial; volatiles removed under vac.; pentane added; filtered through glass fiber filter; concd.; cooled to -30°C; elem. anal.;
DOI:10.1016/S0022-328X(02)01640-6

Reference yield:

: 392-56-3
Hexafluorobenzene

: 61396-34-7
(pentamethylcyclopentadienyl)2ZrH₂

: 87985-79-3
[(η(5)-pentamethylcyclopentadienyl)2ZrHF]

: 301195-57-3
(η5-pentamethylcyclopentadienyl)Zr(C6F5)H

: 494800-76-9
(η5-pentamethylcyclopentadienyl)Zr(C6F5)F

Guidance literature:: In tetrahydrofuran-d8; byproducts: C6F5H; under N2; in NMR tube; Zr complex dissolved in THF-d8; C6F6 (20 equiv.) added; freeze-pump-thaw degassed; sealed under vac.; heated at 85°C for 8 h; not isolated; detd. by (1)H and (19)F NMR spectra and GC-MS; many unidentified C-F activated compds. obtained;
DOI:10.1016/S0022-328X(02)01640-6

Reference yield:

: 61396-34-7
(pentamethylcyclopentadienyl)2ZrH₂

: 301195-57-3
(η5-pentamethylcyclopentadienyl)Zr(C6F5)H

: 7664-39-3,12381-92-9,32057-09-3,74835-82-8
hydrogen fluoride

: 87985-79-3
[(η(5)-pentamethylcyclopentadienyl)2ZrHF]

: (η(5)-C5Me5)2ZrF2

: 494800-76-9
(η5-pentamethylcyclopentadienyl)Zr(C6F5)F

Guidance literature:: In pyridine; pentane; under N2; in polyethylene vessel; equimolar mixt. of two Zr complexes dissolved in pentane; HF-pyridine (70:30) soln. in pentane added at room temp. with stirring; pentane removed under vac.; detd. by (1)H and (19)F NMR spectra; mixt. of (C5Me5)2Zr(C6F5)F, (C5Me5)2ZrHF, (C5Me5)2ZrF2 and small amt. of unidentified species obtained;
DOI:10.1016/S0022-328X(02)01640-6