benzaldehyde O-methyloxime

Base Information

• Chemical Name: benzaldehyde O-methyloxime
• CAS No.: 10229-54-6
• Molecular Formula: C8H9NO
• Molecular Weight: 135.166
• Mol file: 10229-54-6.mol

Synonyms:

Chemical Property of benzaldehyde O-methyloxime

Chemical Property:

• Vapor Pressure: 0.679mmHg at 25°C

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of benzaldehyde O-methyloxime

There total 22 articles about benzaldehyde O-methyloxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

N-methoxylamine hydrochloride (593-56-6) + benzaldehyde (100-52-7) → benzaldehyde O-methyloxime (3376-32-7,10229-53-5,10229-54-6)

Guidance literature:

With sodium carbonate; acetic acid; In methanol; water; for 2h; Heating;

DOI:10.1016/S0040-4039(00)76759-1

Reference yield: 95.0%

O-methyl hydroxylamine hydrochloride + benzaldehyde (100-52-7) → benzaldehyde O-methyloxime (3376-32-7,10229-53-5,10229-54-6)

Guidance literature:

With sodium acetate; In ethanol; water; for 3h; Reflux;

Reference yield: 91.0%

N-benzyl-N-methoxyamine (20056-98-8) → benzaldehyde O-methyloxime (3376-32-7,10229-53-5,10229-54-6)

Guidance literature:

With MS₃ Angstroem; oxygen; sodium acetate; triphenylphosphine; palladium dichloride; In N,N-dimethyl-formamide; at 80 ℃; for 14h; under 760 Torr;

DOI:10.1016/j.tetlet.2006.09.088

upstream raw materials:

N-methoxy-α-phenylnitrone

diethyl-N-methoxyphosphamide

benzaldehyde

N-methoxylamine hydrochloride

Downstream raw materials:

(z)-1-amino-1-phenyl-2-(2-pyridyl)ethene

N,N'-bis(isopropyl)benzamidine

trans-2-phenyl-3-(2-pyridyl)aziridine

phenyl butyl ketone