Technology Process of 2-phenylmethyl-9H-pyrido[3,4-b]indolium triflate
There total 5 articles about 2-phenylmethyl-9H-pyrido[3,4-b]indolium triflate which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]};
In
1,2-dichloro-ethane;
at 80 ℃;
for 15h;
Inert atmosphere;
Molecular sieve;
DOI:10.1002/anie.201201788
- Guidance literature:
-
Multi-step reaction with 2 steps
1: dichloromethane / 20 °C / Inert atmosphere
2: bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]} / 1,2-dichloro-ethane / 15 h / 80 °C / Inert atmosphere; Molecular sieve
With
bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]};
In
dichloromethane; 1,2-dichloro-ethane;
DOI:10.1002/anie.201201788
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; sodium carbonate / 1,4-dioxane; water / 2.5 h / 80 °C / Inert atmosphere
2.1: acetic acid; sodium nitrite / water / 1.5 h / 0 °C / Inert atmosphere
2.2: 0.5 h / 20 °C / Inert atmosphere
3.1: dichloromethane / 20 °C / Inert atmosphere
4.1: bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]} / 1,2-dichloro-ethane / 15 h / 80 °C / Inert atmosphere; Molecular sieve
With
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]}; sodium carbonate; acetic acid; sodium nitrite;
In
1,4-dioxane; dichloromethane; water; 1,2-dichloro-ethane;
1.1: Suzuki coupling;
DOI:10.1002/anie.201201788
