(S)-3-Benzyloxymethyl-6-[4-(tert-butyl-diphenyl-silanyloxy)-3-(tert-butyl-diphenyl-silanyloxymethyl)-butyl]-5-(toluene-4-sulfinyl)-3,4-dihydro-2H-pyran

Base Information

Chemical Name:(S)-3-Benzyloxymethyl-6-[4-(tert-butyl-diphenyl-silanyloxy)-3-(tert-butyl-diphenyl-silanyloxymethyl)-butyl]-5-(toluene-4-sulfinyl)-3,4-dihydro-2H-pyran
CAS No.:113457-88-8
Molecular Formula:C₅₇H₆₈O₅SSi₂
Molecular Weight:921.401
Hs Code.:

(S)-3-Benzyloxymethyl-6-[4-(tert-butyl-diphenyl-silanyloxy)-3-(tert-butyl-diphenyl-silanyloxymethyl)-butyl]-5-(toluene-4-sulfinyl)-3,4-dihydro-2H-pyran

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Chemical Property of (S)-3-Benzyloxymethyl-6-[4-(tert-butyl-diphenyl-silanyloxy)-3-(tert-butyl-diphenyl-silanyloxymethyl)-butyl]-5-(toluene-4-sulfinyl)-3,4-dihydro-2H-pyran

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Technology Process of (S)-3-Benzyloxymethyl-6-[4-(tert-butyl-diphenyl-silanyloxy)-3-(tert-butyl-diphenyl-silanyloxymethyl)-butyl]-5-(toluene-4-sulfinyl)-3,4-dihydro-2H-pyran

There total 7 articles about (S)-3-Benzyloxymethyl-6-[4-(tert-butyl-diphenyl-silanyloxy)-3-(tert-butyl-diphenyl-silanyloxymethyl)-butyl]-5-(toluene-4-sulfinyl)-3,4-dihydro-2H-pyran which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 17.0%

: 100-39-0
benzyl bromide

: 113477-00-2
1-[4-(tert-Butyl-diphenyl-silanyloxy)-3-(tert-butyl-diphenyl-silanyloxymethyl)-butyl]-7-((S)-toluene-4-sulfinyl)-2,6-dioxa-bicyclo[2.2.2]octane

: 113477-01-3
(R)-3-Benzyloxymethyl-6-[4-(tert-butyl-diphenyl-silanyloxy)-3-(tert-butyl-diphenyl-silanyloxymethyl)-butyl]-5-((S)-toluene-4-sulfinyl)-3,4-dihydro-2H-pyran

: 113457-88-8,113477-01-3,148324-35-0,148324-36-1
(S)-3-Benzyloxymethyl-6-[4-(tert-butyl-diphenyl-silanyloxy)-3-(tert-butyl-diphenyl-silanyloxymethyl)-butyl]-5-(toluene-4-sulfinyl)-3,4-dihydro-2H-pyran

Guidance literature:: With trifluoroacetic acid;
DOI:10.1016/S0040-4039(00)96304-4

Reference yield:

: 1519-39-7
(R)-methyl p-tolyl sulfoxide

: 113457-88-8,113477-01-3,148324-35-0,148324-36-1
(S)-3-Benzyloxymethyl-6-[4-(tert-butyl-diphenyl-silanyloxy)-3-(tert-butyl-diphenyl-silanyloxymethyl)-butyl]-5-(toluene-4-sulfinyl)-3,4-dihydro-2H-pyran

Guidance literature:: Multi-step reaction with 5 steps

1: 84 percent

2: 87 percent

4: 91 percent / ZnCl₂

5: 71 percent / trifluoroacetic acid

With trifluoroacetic acid; zinc(II) chloride;
DOI:10.1016/S0040-4039(00)96304-4

Reference yield:

: 113457-95-7
4,4-bis(hydroxymethyl)butanal ethylene acetal

: 113457-88-8,113477-01-3,148324-35-0,148324-36-1
(S)-3-Benzyloxymethyl-6-[4-(tert-butyl-diphenyl-silanyloxy)-3-(tert-butyl-diphenyl-silanyloxymethyl)-butyl]-5-(toluene-4-sulfinyl)-3,4-dihydro-2H-pyran

Guidance literature:: Multi-step reaction with 6 steps

1: 1.)imidazole; 2.) p-TsOH / 2.) acetone

2: 84 percent

3: 87 percent

5: 91 percent / ZnCl₂

6: 71 percent / trifluoroacetic acid

With 1H-imidazole; toluene-4-sulfonic acid; trifluoroacetic acid; zinc(II) chloride;
DOI:10.1016/S0040-4039(00)96304-4