(E)-N-Butyl-1-(2,4,6-tri-tert-butylphenyl)methanimine

Base Information

• Chemical Name: (E)-N-Butyl-1-(2,4,6-tri-tert-butylphenyl)methanimine
• CAS No.: 102737-67-7
• Molecular Formula: C23H39N
• Molecular Weight: 329.569
• DSSTox Substance ID: DTXSID90543971
• Mol file: 102737-67-7.mol

Synonyms:102737-67-7;(E)-N-Butyl-1-(2,4,6-tri-tert-butylphenyl)methanimine;DTXSID90543971

Chemical Property of (E)-N-Butyl-1-(2,4,6-tri-tert-butylphenyl)methanimine

Chemical Property:

• XLogP3: 7.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 7
• Exact Mass: 329.308250248
• Heavy Atom Count: 24
• Complexity: 375

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCN=CC1=C(C=C(C=C1C(C)(C)C)C(C)(C)C)C(C)(C)C

Technology Process of (E)-N-Butyl-1-(2,4,6-tri-tert-butylphenyl)methanimine

There total 10 articles about (E)-N-Butyl-1-(2,4,6-tri-tert-butylphenyl)methanimine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

2,4,6-tri-(tert-butyl)thiobenzaldehyde (84543-57-7) + N-butylamine (109-73-9,85404-21-3) → Butyl-[1-(2,4,6-tri-tert-butyl-phenyl)-meth-(E)-ylidene]-amine (102737-67-7)

Guidance literature:

at 70 ℃;

DOI:10.1039/c39860000071

Reference yield: 48.0%

2,4,6-tri-tert-butylphenyllithium (35383-91-6) + O-t-butyl selenoformate (102737-62-2) + N-butylamine (109-73-9,85404-21-3) → 1,3,5-Tri-tert-butylbenzene (1460-02-2) + 2,4,6-tri(tert-butyl)benzaldehyde (3975-81-3) + Butyl-[1-(2,4,6-tri-tert-butyl-phenyl)-meth-(E)-ylidene]-amine (102737-67-7) + 2-tert-Butoxymethyl-1,3,5-tri-tert-butyl-benzene

Guidance literature:

In tetrahydrofuran; Further byproducts given; Ambient temperature;

DOI:10.1039/c39860000071

Reference yield: 42.0%

2,4,6-Tri-tert-butylselenobenzaldehyde (107396-00-9) + N-butylamine (109-73-9,85404-21-3) → Butyl-[1-(2,4,6-tri-tert-butyl-phenyl)-meth-(E)-ylidene]-amine (102737-67-7) + C38H62Se2 (102737-64-4)

Guidance literature:

In toluene; at 0 ℃; for 0.75h;

DOI:10.1021/ja00197a070

upstream raw materials:

1-bromo-2,4,6-tri-tert-butylbenzene

O-t-butyl selenoformate

2,4,6-tri-(tert-butyl)thiobenzaldehyde

N-butylamine