[2,2-(CO)2-2-(NO)-8-(Ph)-1,1,8-closo-ReC₂B₉H₁₀]

Base Information

Chemical Name:[2,2-(CO)2-2-(NO)-8-(Ph)-1,1,8-closo-ReC₂B₉H₁₀]
CAS No.:1153642-20-6
Molecular Formula:C₁₀H₁₅B₉NO₃Re
Molecular Weight:480.74
Hs Code.:

[2,2-(CO)2-2-(NO)-8-(Ph)-1,1,8-closo-ReC<sub>2</sub>B<sub>9</sub>H<sub>10</sub>]

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Chemical Property of [2,2-(CO)2-2-(NO)-8-(Ph)-1,1,8-closo-ReC₂B₉H₁₀]

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Technology Process of [2,2-(CO)2-2-(NO)-8-(Ph)-1,1,8-closo-ReC₂B₉H₁₀]

There total 2 articles about [2,2-(CO)2-2-(NO)-8-(Ph)-1,1,8-closo-ReC₂B₉H₁₀] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 1153642-10-4
Cs⁽¹⁺⁾*C₂B₉H₁₀C₆H₅Re(CO)3^(1-)=CsC₂B₉H₁₀C₆H₅Re(CO)3

: 7664-93-9
sulfuric acid

: 7632-00-0
sodium nitrite

: 1153642-20-6
[2,2-(CO)2-2-(NO)-8-(Ph)-1,1,8-closo-ReC₂B₉H₁₀]

Guidance literature:: In water; acetonitrile; addn. of aq. NaNO2 and H2SO4 to a soln. of Re complex in acetonitrile/H2O 3:1, react. for 35 min, addn. of more aq. NaNO2 and H2SO4, react. for 90 min; addn. to CH2Cl2 and H2O, washing org. phase with H2O, drying over Na2SO4, evapn. in vac., reverse phase silica gel chromy. (60-100% acetonitrilein H2O);
DOI:10.1021/om8011807

Reference yield: 38.0%

: 1023758-51-1
Na⁽¹⁺⁾*C₂B₉H₁₀C₆H₅Re(CO)3^(1-)=NaC₂B₉H₁₀C₆H₅Re(CO)3

: 7664-93-9
sulfuric acid

: 7632-00-0
sodium nitrite

: 1153642-20-6
[2,2-(CO)2-2-(NO)-8-(Ph)-1,1,8-closo-ReC₂B₉H₁₀]

Guidance literature:: In water; addn. of aq. NaNO2 and H2SO4 to a soln. of (186/188)Re complex, react. for 5 min; C18 solid phase extn. carteidge, flushing with aq. acetonitrile 60%, then neat acetonitrile; identified by radio-HPLC (Nucleosil C18 column, 85-98% acetonitrile in H2O 0-17 min, 98% acetonitrile in H2O 17-20 min);
DOI:10.1021/om8011807