trans-11,12-dihydroxy-11,12,13,14-tetrahydrobenzochrysene

Base Information

• Chemical Name: trans-11,12-dihydroxy-11,12,13,14-tetrahydrobenzochrysene
• CAS No.: 122048-32-2
• Molecular Formula: C₂₂H₁₈O₂
• Molecular Weight: 314.384

Synonyms:

Chemical Property of trans-11,12-dihydroxy-11,12,13,14-tetrahydrobenzochrysene

Chemical Property:

Purity/Quality:

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Technology Process of trans-11,12-dihydroxy-11,12,13,14-tetrahydrobenzochrysene

There total 4 articles about trans-11,12-dihydroxy-11,12,13,14-tetrahydrobenzochrysene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

13,14-dihydrobenzochrysene (122048-29-7) → cis-11,12-dihydroxy-11,12,13,14-tetrahydrobenzochrysene (122048-32-2,122048-33-3,122090-51-1,122090-52-2) + trans-11,12-dihydroxy-11,12,13,14-tetrahydrobenzochrysene (122048-32-2,122048-33-3,122090-51-1,122090-52-2) + 3-Chloro-benzoic acid 12-hydroxy-11,12,13,14-tetrahydro-benzo[g]chrysen-11-yl ester (122048-31-1,122048-43-5)

Guidance literature:

With hydrogenchloride; sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; Multistep reaction; 1.) CH₂Cl₂, 50 min, 2.) THF, RT, 3 h;

DOI:10.1021/jo00276a009

Reference yield:

13,14-dihydrobenzochrysene (122048-29-7) → cis-11,12-dihydroxy-11,12,13,14-tetrahydrobenzochrysene (122048-32-2,122048-33-3,122090-51-1,122090-52-2) + trans-11,12-dihydroxy-11,12,13,14-tetrahydrobenzochrysene (122048-32-2,122048-33-3,122090-51-1,122090-52-2) + 3-Chloro-benzoic acid 12-hydroxy-11,12,13,14-tetrahydro-benzo[g]chrysen-11-yl ester (122048-31-1,122048-43-5)

Guidance literature:

With hydrogenchloride; sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; Multistep reaction; 1.) CH₂Cl₂, 50 min, 2.) THF, RT, 3 h;

DOI:10.1021/jo00276a009

Reference yield:

13,14-dihydrobenzochrysene (122048-29-7) + 3-chloro-benzenecarboperoxoic acid (937-14-4) → 11,12,13,14-tetrahydrobenzochrysene 11,12-acetonide (122048-34-4) + trans-11,12-dihydroxy-11,12,13,14-tetrahydrobenzochrysene (122048-32-2,122048-33-3,122090-51-1,122090-52-2) + 3-Chloro-benzoic acid 12-hydroxy-11,12,13,14-tetrahydro-benzo[g]chrysen-11-yl ester (122048-31-1,122048-43-5)

Guidance literature:

Multistep reaction;

DOI:10.1021/jo00276a009

upstream raw materials:

13,14-dihydrobenzochrysene

3-chloro-benzenecarboperoxoic acid

acetone

Downstream raw materials:

trans-11,12-bis((4-(dimethylamino)benzoyl)oxy)-11,12,13,14-tetrahydrobenzochrysene

trans-11S,12S-bis(((-)-menthyloxy)acetoxy)-11,12,13,14-tetrahydrobenzochrysene

trans-11R,12R-bis(((-)-menthyloxy)acetoxy)-11,12,13,14-tetrahydrobenzochrysene

trans-11,12-bis(((-)-menthyloxy)acetoxy)-11,12,13,14-tetrahydrobenzochrysene

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