trans epoxystyryl p-tolyl sulphone

Base Information

• Chemical Name: trans epoxystyryl p-tolyl sulphone
• CAS No.: 54897-34-6
• Molecular Formula: C₁₅H₁₄O₃S
• Molecular Weight: 274.34
• Mol file: 54897-34-6.mol

Synonyms:

Chemical Property of trans epoxystyryl p-tolyl sulphone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans epoxystyryl p-tolyl sulphone

There total 3 articles about trans epoxystyryl p-tolyl sulphone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

1-((2-(tert-butylperoxy)-2-phenylethyl)sulfonyl)-4-methylbenzene → trans epoxystyryl p-tolyl sulphone (25095-22-1,54607-00-0,54897-34-6)

Guidance literature:

With sodium hydride; In tetrahydrofuran; at 0 ℃; for 5h; Inert atmosphere;

DOI:10.1016/j.tetlet.2018.09.045

Reference yield: 65.0%

chloromethyl p-tolylsulfone (7569-26-8) + benzaldehyde (100-52-7) → trans epoxystyryl p-tolyl sulphone (25095-22-1,54607-00-0,54897-34-6)

Guidance literature:

With sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride; In acetonitrile; for 1h; Ambient temperature;

DOI:10.1055/s-1983-30449

Reference yield:

1-methyl-4-[(E)-2-phenylethenesulfonyl]benzene (16212-08-1) → trans epoxystyryl p-tolyl sulphone (25095-22-1,54607-00-0,54897-34-6)

Guidance literature:

With alkaline H₂O₂; In methanol; at 25 - 40 ℃; Rate constant; Kinetics; Thermodynamic data; E_a, ΔH(excit.), ΔS(excit.), ΔG(excit.); var. temp.;

upstream raw materials:

1-methyl-4-[(E)-2-phenylethenesulfonyl]benzene

chloromethyl p-tolylsulfone

benzaldehyde

Downstream raw materials:

Methyl-[(E)-2-phenyl-2-(toluene-4-sulfonyl)-vinyl]-o-tolyl-amine

Methyl-phenyl-[(E)-2-phenyl-2-(toluene-4-sulfonyl)-vinyl]-amine

4-[(E)-2-Phenyl-2-(toluene-4-sulfonyl)-vinyl]-morpholine

toluene-4-sulfonic acid