trans-dichlorobis[tris[3,5-bis(trifluoromethyl)phenyl]phosphane]platinum(II)

Base Information

• Chemical Name: trans-dichlorobis[tris[3,5-bis(trifluoromethyl)phenyl]phosphane]platinum(II)
• CAS No.: 100570-22-7
• Molecular Formula: C₄₈H₁₈Cl₂F₃₆P₂Pt
• Molecular Weight: 1606.55
• Mol file: 100570-22-7.mol

Synonyms:

Chemical Property of trans-dichlorobis[tris[3,5-bis(trifluoromethyl)phenyl]phosphane]platinum(II)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of trans-dichlorobis[tris[3,5-bis(trifluoromethyl)phenyl]phosphane]platinum(II)

There total 3 articles about trans-dichlorobis[tris[3,5-bis(trifluoromethyl)phenyl]phosphane]platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

dichloro(1,5-cyclooctadiene)platinum(ll) (12080-32-9) + tris<3,5-bis(trifluoromethyl)phenyl>phosphane (175136-62-6) → trans-dichlorobis[tris[3,5-bis(trifluoromethyl)phenyl]phosphane]platinum(II) (100570-22-7)

Guidance literature:

In dichloromethane; N2-atmosphere; phosphane soln. added dropwise to complex soln. at room temp.; refluxed for 1 h; stirred for 2 h at room temp.; solvent removed in vacuo; dissolved in CH2Cl2 and layered with ether; crystn. at -20°C for 20 h; washed with CH2Cl2/ether and acetone; dried in vacuo over silica gel; elem. anal.;

Reference yield: 85.0%

potassium tetrachloroplatinate(II) (10025-99-7) + tris<3,5-bis(trifluoromethyl)phenyl>phosphane (175136-62-6) → trans-dichlorobis[tris[3,5-bis(trifluoromethyl)phenyl]phosphane]platinum(II) (100570-22-7)

Guidance literature:

In water; N2-atmosphere;, stirred at room temp. until colourless suspension; crystals isolated, washed with water and cold ethanol, and dried at room temp. over P2O5;

Reference yield: 72.0%

dichlorobis(dimethylsulfide)platinum(II) (17457-51-1,17836-09-8,55449-91-7) + tris<3,5-bis(trifluoromethyl)phenyl>phosphane (175136-62-6) → trans-dichlorobis[tris[3,5-bis(trifluoromethyl)phenyl]phosphane]platinum(II) (100570-22-7)

Guidance literature:

In further solvent(s); (N2); addn. of phosphine to a soln. of platinum complex in pentafluorobenzene, stirring for 24 h at room temp.; evapn., addn. of toluene, stirring for 30 min, filtration, washing ppt. with toluene; elem. anal.;

DOI:10.1039/b418193j

upstream raw materials:

dichloro(1,5-cyclooctadiene)platinum(ll)

tris<3,5-bis(trifluoromethyl)phenyl>phosphane

dichlorobis(dimethylsulfide)platinum(II)

potassium tetrachloroplatinate(II)