B,B',B''-trimethyl-N,N',N''-tri-m-tolylborazine

Base Information

• Chemical Name: B,B',B''-trimethyl-N,N',N''-tri-m-tolylborazine
• CAS No.: 749-89-3
• Molecular Formula: C₂₄H₃₀B₃N₃
• Molecular Weight: 392.955
• Mol file: 749-89-3.mol

Synonyms:

Chemical Property of B,B',B''-trimethyl-N,N',N''-tri-m-tolylborazine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of B,B',B''-trimethyl-N,N',N''-tri-m-tolylborazine

There total 2 articles about B,B',B''-trimethyl-N,N',N''-tri-m-tolylborazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

methyl magnesium iodide (917-64-6) + (BClN(3-CH3-C6H4))3 (6997-67-7) → B,B',B''-trimethyl-N,N',N''-tri-m-tolylborazine (749-89-3)

Guidance literature:

In diethyl ether; under dry nitrogen, addn. of a suspn. of CH3MgI to a soln. of B-compound, refluxing for 1 h; cooling, addn. of an aq. soln. of NH4Cl, filtn., washing (Et2O), drying organic layers (CaCl2), evapn. to dryness under reduced pressure;

DOI:10.1016/0022-328X(94)80079-0

Reference yield:

1-amino-3-methylbenzene (108-44-1) → B,B',B''-trimethyl-N,N',N''-tri-m-tolylborazine (749-89-3)

Guidance literature:

Multi-step reaction with 2 steps

1: toluene

2: diethyl ether

In diethyl ether; toluene;

DOI:10.1016/0022-328X(94)80079-0

Reference yield: 18.0%

B,B',B''-trimethyl-N,N',N''-tri-m-tolylborazine (749-89-3) + chromium(0) hexacarbonyl (199620-14-9,13007-92-6) → (η6-B,B',B''-trimethyl-N,N',N''-tri-m-tolylborazine)tricarbonylchromium

Guidance literature:

In tetrahydrofuran; dibutyl ether; under dry argon, heating for 24 h; cooling, filtn., evapn. to dryness, chromy.;

DOI:10.1016/0022-328X(94)80079-0

upstream raw materials:

methyl magnesium iodide

(BClN(3-CH₃-C₆H₄))3

1-amino-3-methylbenzene