[(CH3C(CH2P(C6H5)2)3)Co(I)-(η4-2-methylbuta-1,3-diene)] hexafluorophosphate

Base Information

Chemical Name:[(CH3C(CH2P(C6H5)2)3)Co(I)-(η4-2-methylbuta-1,3-diene)] hexafluorophosphate
CAS No.:265116-95-8
Molecular Formula:C₄₆H₄₇CoP₃*F₆P
Molecular Weight:896.758
Hs Code.:

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Chemical Property of [(CH3C(CH2P(C6H5)2)3)Co(I)-(η4-2-methylbuta-1,3-diene)] hexafluorophosphate

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Technology Process of [(CH3C(CH2P(C6H5)2)3)Co(I)-(η4-2-methylbuta-1,3-diene)] hexafluorophosphate

There total 2 articles about [(CH3C(CH2P(C6H5)2)3)Co(I)-(η4-2-methylbuta-1,3-diene)] hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 60969-19-9
thallium(I) hexafluorophosphate

: 37701-79-4
[1,1,1,-tris((diphenylphosphino)methyl)ethane]cobalt(I) chloride

: 78-79-5,9003-31-0
isoprene

: 265116-95-8
[(CH3C(CH2P(C6H5)2)3)Co(I)-(η4-2-methylbuta-1,3-diene)] hexafluorophosphate

Guidance literature:: In tetrahydrofuran; byproducts: TlCl; Sonication; under Ar, Schlenk techniques; to suspn. of (MeC(CH2PPh2)3)Co(I)Cl and TlPF6 in THF isoprene was added; 10 min ultrasonic irradn.; solvent evapd. in vac., residue redissolved in CH2Cl2, filtered, solvent evapd.; chromy. (silica gel, Et2O/CH2Cl2);;
DOI:10.1002/(SICI)1099-0682(199903)2000:3<523::AID-EJIC523>3.0.CO;2-U

Reference yield: 64.0%

: 17084-13-8
potassium hexafluorophosphate

: cobalt(II) tetrafluoroborate hydrate

: 22031-12-5
[2-((diphenylphospino)methyl)-2-methyl-1,3-propanediyl]bis[diphenylphosphine]

: 78-79-5,9003-31-0
isoprene

: 265116-95-8
[(CH3C(CH2P(C6H5)2)3)Co(I)-(η4-2-methylbuta-1,3-diene)] hexafluorophosphate

Guidance literature:: With Zn; In tetrahydrofuran; ethanol; dichloromethane; byproducts: ZnCl2, KBF4; Sonication; under Ar, Schlenk techniques; isoprene and 5-fold excess of activated Zn powder were added to soln. of Co(BF4)2 and MeC(CH2PPh2)3 in CH2Cl2/EtOH; 5 min ultrasonic irradn.; solvents evapd. in vac., 3-fold excess of KPF6 was added to residue in THF; solvent evapd. in vac., residue redissolved in CH2Cl2, filtered, concd.to dryness; chromy. (silica gel, Et2O/CH2Cl2);;
DOI:10.1002/(SICI)1099-0682(199903)2000:3<523::AID-EJIC523>3.0.CO;2-U