RuCl(P(C₆H₅)2CH₂CH₂CH₂P(C₆H₅)2)2⁽¹⁺⁾*BF₄^(1-)=RuCl(P(C₆H₅)2CH₂CH₂CH₂P(C₆H₅)2)2BF₄

Base Information

• Chemical Name: RuCl(P(C₆H₅)2CH₂CH₂CH₂P(C₆H₅)2)2⁽¹⁺⁾*BF₄^(1-)=RuCl(P(C₆H₅)2CH₂CH₂CH₂P(C₆H₅)2)2BF₄
• CAS No.: 202187-69-7
• Molecular Formula: BF₄*C₅₄H₅₂ClP₄Ru
• Molecular Weight: 1048.23
• Mol file: 202187-69-7.mol

Synonyms:

Chemical Property of RuCl(P(C₆H₅)2CH₂CH₂CH₂P(C₆H₅)2)2⁽¹⁺⁾*BF₄^(1-)=RuCl(P(C₆H₅)2CH₂CH₂CH₂P(C₆H₅)2)2BF₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of RuCl(P(C₆H₅)2CH₂CH₂CH₂P(C₆H₅)2)2⁽¹⁺⁾*BF₄^(1-)=RuCl(P(C₆H₅)2CH₂CH₂CH₂P(C₆H₅)2)2BF₄

There total 1 articles about RuCl(P(C₆H₅)2CH₂CH₂CH₂P(C₆H₅)2)2⁽¹⁺⁾*BF₄^(1-)=RuCl(P(C₆H₅)2CH₂CH₂CH₂P(C₆H₅)2)2BF₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

tris(triphenylphosphine)ruthenium(II) chloride (15529-49-4,41756-81-4) + ammonium tetrafluroborate (13826-83-0) + 1,3-bis-(diphenylphosphino)propane (6737-42-4) → RuCl(P(C6H5)2CH2CH2CH2P(C6H5)2)2(1+)*BF4(1-)=RuCl(P(C6H5)2CH2CH2CH2P(C6H5)2)2BF4 (202187-69-7)

Guidance literature:

In ethanol; suspn. of Ru-complex, ligand, NH4BF4 in EtOH was stirred at reflux under1 atm of N2 for 4 h; solvent was evapd., extd. with CH2Cl2, i-PrOH was added; elem. anal.;

DOI:10.1021/ic000799f

Reference yield: 54.0%

trans-[RuCl(η2-H2)(dppp)2]BF4 (321695-91-4) + cis-{tungsten(dinitrogen)2(P(methyl)2Ph)4} + RuCl(P(C6H5)2CH2CH2CH2P(C6H5)2)2(1+)*BF4(1-)=RuCl(P(C6H5)2CH2CH2CH2P(C6H5)2)2BF4 (202187-69-7) → trans-chlorohydrido-di-1,3-bis(diphenylphosphino)propaneruthenium(II) (60879-59-6) + ammonia (7664-41-7)

Guidance literature:

In 1,2-dichloro-ethane; benzene; Ru-complexes were placed in flask under 1 atm of H2, dichloroethane and benzene were added, stirred at 55°C for 15 min, W-complex was added, stirred at 55°C for 24 h;

DOI:10.1021/ic000799f

upstream raw materials:

tris(triphenylphosphine)ruthenium(II) chloride

ammonium tetrafluroborate

1,3-bis-(diphenylphosphino)propane

Downstream raw materials:

trans-chlorohydrido-di-1,3-bis(diphenylphosphino)propaneruthenium(II)

ammonia