(η-cyclopentadienyl)(1,2-bis(diphenylphosphino)ethane)(diphenyl sulfide)ruthenium tetrafluoroborate

Base Information

• Chemical Name: (η-cyclopentadienyl)(1,2-bis(diphenylphosphino)ethane)(diphenyl sulfide)ruthenium tetrafluoroborate
• CAS No.: 156762-47-9
• Molecular Formula: BF₄*C₄₃H₃₉P₂RuS
• Molecular Weight: 837.671
• Mol file: 156762-47-9.mol

Synonyms:

Chemical Property of (η-cyclopentadienyl)(1,2-bis(diphenylphosphino)ethane)(diphenyl sulfide)ruthenium tetrafluoroborate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (η-cyclopentadienyl)(1,2-bis(diphenylphosphino)ethane)(diphenyl sulfide)ruthenium tetrafluoroborate

There total 1 articles about (η-cyclopentadienyl)(1,2-bis(diphenylphosphino)ethane)(diphenyl sulfide)ruthenium tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

silver tetrafluoroborate (14104-20-2) + (η-cyclopentadienyl)(1,2-bis(di-p-tolylphosphino)ethane)ruthenium chloride (156791-00-3) + diphenyl sulfide (139-66-2) → (η-cyclopentadienyl)(1,2-bis(diphenylphosphino)ethane)(diphenyl sulfide)ruthenium tetrafluoroborate (156762-47-9)

Guidance literature:

In acetone; addn. of AgBF4 in acetone to a soln. of Ru-complex and Ph2S in acetone under an inert atmosphere, stirring until mixt. turns yellow (ca. 1 h); filtn., evapn. of filtrate under reduced pressure, extn. with CH2Cl2, purification through a short florisil column, elution with n-hexane, drying under vacuum, recrystn. from ethanol/ether, washing with n-hexane andether, elem. anal.;

DOI:10.1016/0022-328X(94)80164-9

upstream raw materials:

silver tetrafluoroborate

(η-cyclopentadienyl)(1,2-bis(di-p-tolylphosphino)ethane)ruthenium chloride

diphenyl sulfide