Ru[(CH₃)2C₆H₃NCHCHNC₆H₃(CH₃)2]2Cl₂

Base Information

• Chemical Name: Ru[(CH₃)2C₆H₃NCHCHNC₆H₃(CH₃)2]2Cl₂
• CAS No.: 90742-41-9
• Molecular Formula: C₃₆H₄₀Cl₂N₄Ru
• Molecular Weight: 700.716
• Mol file: 90742-41-9.mol

Synonyms:

Chemical Property of Ru[(CH₃)2C₆H₃NCHCHNC₆H₃(CH₃)2]2Cl₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Ru[(CH₃)2C₆H₃NCHCHNC₆H₃(CH₃)2]2Cl₂

There total 1 articles about Ru[(CH₃)2C₆H₃NCHCHNC₆H₃(CH₃)2]2Cl₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

trans-{RuCl2(C6H5CN)4} (21503-87-7,51014-03-0) + (1E,2E)-N1,N2-bis(2,6-dimethylphenyl)ethane-1,2-diimine (134780-63-5) → Ru[(CH3)2C6H3NCHCHNC6H3(CH3)2]2Cl2 (90742-41-9) + Ru[(CH3)2C6H3NCHCHNC6H3(CH3)2]2Cl2

Guidance literature:

In diethylene glycol; heating Ru-complex in the presence of excess ligand to the boiling point of diglyme within a period of 30 min under N2; boiling for further 1h;cooling; crystn. of trans complex overnight at ambient temp. from the blue violet soln.; filtration; even after several hours heating of the filtrate nocis complex was detected;

Reference yield: 86.0%

bis(2,6-xylyl-diazadiene)-bis-chloro-ruthenium (90742-41-9) + potassium (7440-09-7) → di-potassium-bis(2,6-xylyldiazadiene)ruthenate

Guidance literature:

In tetrahydrofuran; Ar; 3-4 mol equivalent K; room temp.; 10 h; stirring;; evapd.; dissolved in THF; filtered; pentane added; pptd.; elem. anal.;;

DOI:10.1016/0022-328X(91)83049-A

Reference yield: 81.0%

bis(2,6-xylyl-diazadiene)-bis-chloro-ruthenium (90742-41-9) + ethene (74-85-1) → {N(C6H3(CH3)2)CHCHN(C6H3(CH3)2)}2Ru(C2H4) (123594-73-0)

Guidance literature:

With potassium; In tetrahydrofuran; under C2H4; soln. of Ru-complex stirred with slight excess of potassium sand (8 h, room temp.), color change to green; evapn., extn. (toluene), concn., cooling (-20°C);

upstream raw materials:

trans-{RuCl₂(C₆H₅CN)4}

(1E,2E)-N¹,N²-bis(2,6-dimethylphenyl)ethane-1,2-diimine

Downstream raw materials:

{N(C₆H₃(CH₃)2)CHCHN(C₆H₃(CH₃)2)}2Ru(C₂H₄)

bis(2,6-xylyldiazadiene)ruthenium

{N(C₆H₃(CH₃)2)CHCHN(C₆H₃(CH₃)2)}Ru{N(C₆H₃(CH₃)2)CHCHN(C₆H₃(CH₃)2)CH₂CHCHCH₂}

Ru{N(C₆H₃(CH₃)2)CHCHN(C₆H₃(CH₃)2)}2(CO)