bis(triphenylphosphite)palladium⁽⁰⁾

Base Information

Chemical Name:bis(triphenylphosphite)palladium⁽⁰⁾
CAS No.:90144-54-0
Molecular Formula:C₃₆H₃₀O₆P₂Pd
Molecular Weight:726.998
Hs Code.:

bis(triphenylphosphite)palladium<sup>(0)</sup>

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of bis(triphenylphosphite)palladium⁽⁰⁾

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Technology Process of bis(triphenylphosphite)palladium⁽⁰⁾

There total 1 articles about bis(triphenylphosphite)palladium⁽⁰⁾ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.0%

: η3-allylbis(triphenylphosphite)palladium(II) hexafluorophosphate

: 917-54-4
methyllithium

: 90144-54-0
bis(triphenylphosphite)palladium⁽⁰⁾

Guidance literature:: With ethanol; In tetrahydrofuran; diethyl ether; byproducts: propylene; dropwise addn. of 4 equiv MeLi in Et2O to a colorless soln. of the Pd(II) compd. in THF (room temp., under Ar), developing of a yellow color, decompn. of excess MeLi by addn. of dry ethanol, removal of solvent and volatile by-products (reduced pressure); addn. of dry ethanol to the yellow oil, cooling (-78°C), filtration of white ppt., washing (1. dry ethanol, 2 times; 2. dry pentane, 2 times; -78°C), drying (vac.), recrystn. (acetone, -30°C); elem. anal.;
DOI:10.1016/0022-328X(89)85347-1

Reference yield: 56.0%

: 90144-54-0
bis(triphenylphosphite)palladium⁽⁰⁾

: 98-88-4
benzoyl chloride

: chlorobenzoylbis(triphenylphosphite)palladium

Guidance literature:: In toluene; dropwise addn. of PhCOCl to a soln. of ((PhO)3P)2Pd in toluene (-78°C, under Ar), warming to room temp., stirring (5 h), removing of solvent (reduced pressure), addn. of EtOH; filtration of white powder (fine frit), washing (dry pentane), drying (vac.); elem. anal.;
DOI:10.1016/0022-328X(89)85347-1