[Ru(CO)(dimethylphenylphosphine)3(H)2]

Base Information

• Chemical Name: [Ru(CO)(dimethylphenylphosphine)3(H)2]
• CAS No.: 93557-27-8
• Molecular Formula: C₂₅H₃₅OP₃Ru
• Molecular Weight: 545.544
• Mol file: 93557-27-8.mol

Synonyms:

Chemical Property of [Ru(CO)(dimethylphenylphosphine)3(H)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Ru(CO)(dimethylphenylphosphine)3(H)2]

There total 6 articles about [Ru(CO)(dimethylphenylphosphine)3(H)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[Ru(CO)(Et)(dimethylphenylphosphine)3H] (812667-15-5,813431-82-2) + hydrogen (1333-74-0) → [Ru(CO)(dimethylphenylphosphine)3(H)2] (93557-27-8)

Guidance literature:

In ⁽²⁾H₈-toluene; byproducts: EtH; degassing of soln. of Ru(CO)(H)Et(PMe2Ph)3 in C6D5CD3 in NMR tube; refreezing; introduction of H2 at 1 atm; warming to 250 K; shaking; placing in NMR probe, heating to 270 K; monitoring by NMR;

DOI:10.1039/b411600c

Reference yield:

[Ru(CO)(Et)(dimethylphenylphosphine)3H] (812667-15-5,813431-82-2) + hydrogen (1333-74-0) + Dimethyl(phenyl)phosphine (672-66-2) → [Ru(CO)(dimethylphenylphosphine)3(H)2] (93557-27-8)

Guidance literature:

In ⁽²⁾H₈-toluene; byproducts: ethane; (N2); mixing of soln. of Ru(H)(CO)Et(PMe2Ph)3 in CD3C6D5 with PMe2Ph at 270 K; treatment with H2 at 260 K; monitoring by NMR;

DOI:10.1039/b411600c

Reference yield:

sodium tetrahydroborate (16940-66-2) + RuH(BH4)(P(CH3)2C6H5)3 → [Ru(CO)(dimethylphenylphosphine)3(H)2] (93557-27-8)

Guidance literature:

In ethanol; to soln. of complex was added NaBH4, soln. was refluxed under N2 for 1 h; residue was extd. with benzene, oil was dissolved in EtOH an soln. was cooled; NMR, IR;

DOI:10.1016/S0020-1693(00)82346-4

upstream raw materials:

[Ru(η2-BH4)(CO)H(PMe2Ph)2]

Dimethyl(phenyl)phosphine

sodium tetrahydroborate

[Ru(CO)2(η3-C3H5)(PMe2Ph)2]BF4

Downstream raw materials:

cis-(PhMe₂P)3Ru(II)(CO)Cl₂