bis(N-allylcyclohexylcarbodithioato)nickel(II)

Base Information

• Chemical Name: bis(N-allylcyclohexylcarbodithioato)nickel(II)
• CAS No.: 1395880-11-1
• Molecular Formula: C₂₀H₃₂N₂NiS₄
• Molecular Weight: 487.441
• Mol file: 1395880-11-1.mol

Synonyms:

Chemical Property of bis(N-allylcyclohexylcarbodithioato)nickel(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis(N-allylcyclohexylcarbodithioato)nickel(II)

There total 1 articles about bis(N-allylcyclohexylcarbodithioato)nickel(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

carbon disulfide (75-15-0,12122-00-8) + N-Allylcyclohexylamin (6628-00-8) + nickel(II) chloride hexahydrate → bis(N-allylcyclohexylcarbodithioato)nickel(II) (1395880-11-1)

Guidance literature:

In ethanol; water; mixt. of amine and CS2 in EtOH kept at -5°C for 10 min; aq. soln.of NiCl2 slowly added under stirring; ppt. filtered off, washed with water and ether, dried over CaCl2; elem. anal.;

DOI:10.1002/zaac.201200103

Reference yield: 75.0%

ammonium thiocyanate + nickel(II) chloride hexahydrate + bis(N-allylcyclohexylcarbodithioato)nickel(II) (1395880-11-1) + triphenylphosphine (603-35-0) → (N-allylcyclohexylcarbodithioato)(thiocyanato-N)(triphenylphosphine)nickel(II) (1395880-12-2)

Guidance literature:

In methanol; acetonitrile; mixt. of Ni complex, PPh3, NiCl2*6H2O and NH4SCN heated at reflux in MeCN/MeOH (1/1) for 3 h; soln. concd. and filtered, filtrate allowed to evap., ppt. filtered off,dried over CaCl2, recrystd. from MeCN/MeOH; elem. anal.;

DOI:10.1002/zaac.201200103

Reference yield: 75.0%

ammonium perchlorate (7790-98-9) + nickel(II) chloride hexahydrate + bis(N-allylcyclohexylcarbodithioato)nickel(II) (1395880-11-1) + ethyl acetate (141-78-6) + triphenylphosphine (603-35-0) → bis(triphenylphosphine)(N-allylcyclohexylcarbodithioato)nickel(II) perchlorate - ethyl acetate (1/0.5)

Guidance literature:

In dichloromethane; ethyl acetate; mixt. of Ni complex, PPh3, NiCl2*6H2O and NH4ClO4 heated at reflux in CH2Cl2/EtOAc (3/1) for ca. 2 h; soln. concd. and filtered, filtrate allowed to evap., ppt. filtered, dried, recrystd. from CH2Cl2/EtOAc; elem. anal.;

DOI:10.1002/zaac.201200103

upstream raw materials:

carbon disulfide

N-Allylcyclohexylamin

Downstream raw materials:

(N-allylcyclohexylcarbodithioato)(thiocyanato-N)(triphenylphosphine)nickel(II)

Refernces