selenido(5,10,15,20-tetra-p-tolylporphyrinato)molybdenum(IV)

Base Information

Chemical Name:selenido(5,10,15,20-tetra-p-tolylporphyrinato)molybdenum(IV)
CAS No.:165070-96-2
Molecular Formula:C₄₈H₃₆MoN₄Se
Molecular Weight:843.741
Hs Code.:

Synonyms:

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Chemical Property of selenido(5,10,15,20-tetra-p-tolylporphyrinato)molybdenum(IV)

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Technology Process of selenido(5,10,15,20-tetra-p-tolylporphyrinato)molybdenum(IV)

There total 3 articles about selenido(5,10,15,20-tetra-p-tolylporphyrinato)molybdenum(IV) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 17.0%

: sodium selenide

: 64024-40-4
(meso-tetra-p-tolylporphyrinato)MoCl₂

: 64024-42-6
Mo(IV)(O)(ttp)

: 165070-96-2
selenido(5,10,15,20-tetra-p-tolylporphyrinato)molybdenum(IV)

Guidance literature:: In tetrahydrofuran; byproducts: NaCl; inert atmosphere; stirring (40 - 50°C, 24 h); cooling (room temp.), evapn. to dryness, dissoving (toluene), chromy. (neutral alumina/toluene), collection orange/red band, solvent removal (vac.), dissloving in toluene, layering (hexanes), drying (vac.); elem. anal.;

Reference yield:

: 7782-49-2
selenium

: 64024-40-4
(meso-tetra-p-tolylporphyrinato)MoCl₂

: 501-65-5
diphenyl acetylene

: 165070-96-2
selenido(5,10,15,20-tetra-p-tolylporphyrinato)molybdenum(IV)

Guidance literature:: With LiAlH₄; In tetrahydrofuran; toluene; byproducts: diphenylacetylene; inert atmosphere; stirring mixt. of Mo-complex, LiAlH4 and PhCCPh (40 -50°C, 45 min), cooling to room temp., solvent removal (vac.), dissolving in toluene, filtration, Se addn. (in toluene), stirring (50 - 60°C, 48 h); cooling to room temp., solvent removal (vac.), dissolving in toluene, chromy. (neutral alumina/toluene), collection of orange-red band, solventremoval (vac.), crystn. (PhMe/hexanes); mixt. with Ph2C2-complex not sepd.;

Reference yield:

: (meso-tetra-p-tolylporphyrinato)Mo(η2-PhC2Ph)

: 132491-16-8
(TpTP)SnSe

: 129390-30-3
(meso-tetra-p-tolylporphyrinato)Sn

: 165070-96-2
selenido(5,10,15,20-tetra-p-tolylporphyrinato)molybdenum(IV)

Guidance literature:: In benzene-d6; byproducts: diphenylacetylene; N2 atmosphere, sealed NMR-tube; room temp., 2 d; not isolated, detd. by (1)H-NMR spectroscopy;