diphenyl[(1S,2R,3S,4R)-3-(1-methoxymethyl)bicyclo[2.2.1]heptan-2-yl]tin hydride

Base Information

Chemical Name:diphenyl[(1S,2R,3S,4R)-3-(1-methoxymethyl)bicyclo[2.2.1]heptan-2-yl]tin hydride
CAS No.:203380-22-7
Molecular Formula:C₂₁H₂₆OSn
Molecular Weight:413.147
Hs Code.:

Synonyms:

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Chemical Property of diphenyl[(1S,2R,3S,4R)-3-(1-methoxymethyl)bicyclo[2.2.1]heptan-2-yl]tin hydride

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Technology Process of diphenyl[(1S,2R,3S,4R)-3-(1-methoxymethyl)bicyclo[2.2.1]heptan-2-yl]tin hydride

There total 1 articles about diphenyl[(1S,2R,3S,4R)-3-(1-methoxymethyl)bicyclo[2.2.1]heptan-2-yl]tin hydride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 16940-66-2
sodium tetrahydroborate

: 203380-20-5
(1S,2R,3S,4R)-3-methoxymethyl-2-triphenylstannylbicyclo[2.2.1]heptane(-)

: 7553-56-2,12190-71-5,8031-47-8
iodine

: 203380-22-7
diphenyl[(1S,2R,3S,4R)-3-(1-methoxymethyl)bicyclo[2.2.1]heptan-2-yl]tin hydride

Guidance literature:: In dichloromethane; I2 addn. to Sn-compd. soln. (DCM), stirring 1 h at room temp., concn. (reduced pressure), B-compd. soln. (EtOH), after 1 h mixt. partitioning between satd. aq. NH4Cl and Et2O, aq. phase extn. (Et2O), extract drying (MgSO4), concn. (reduced pressure);
DOI:10.1039/a706293a

Reference yield: 60.0%

: 203380-22-7
diphenyl[(1S,2R,3S,4R)-3-(1-methoxymethyl)bicyclo[2.2.1]heptan-2-yl]tin hydride

: 100-52-7
benzaldehyde

: [[(1S,2R,3S,4R)-3-methoxymethylbicyclo[2.2.1]heptan-2-yl]-(diphenyl)stannyl]phenylmethanol

: ((C₆H₅)2SnCHCH(CH₂OCH₃)C₄H₆CH₂)2

Guidance literature:: With BuLi; i-Pr₂NH; aq. NH₄Cl; In tetrahydrofuran; hexane; BuLi soln. (hexane) addn. to i-Pr2NH soln. (THF) at 0°C, stirring20 min, cooling to -78°C, Sn-compd. addn., stirring 5 min, aldeh yde addn., stirring 20 min, aq. satd. NH4Cl addn., warming to room temp., extn. (Et2O), org. phase drying; (MgSO4), concn. (reduced pressure), residue chromy. (hexane/Et2O 9:1);
DOI:10.1039/a706293a