bis(cyclohexylisocyanide)gold(I) bis(phenylene-1,2-dithiolato)aurate(III)

Base Information

• Chemical Name: bis(cyclohexylisocyanide)gold(I) bis(phenylene-1,2-dithiolato)aurate(III)
• CAS No.: 439867-23-9
• Molecular Formula: C₁₂H₈AuS₄*C₁₄H₂₂AuN₂
• Molecular Weight: 892.735
• Mol file: 439867-23-9.mol

Synonyms:

Chemical Property of bis(cyclohexylisocyanide)gold(I) bis(phenylene-1,2-dithiolato)aurate(III)

Chemical Property:

Purity/Quality:

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Useful:

Technology Process of bis(cyclohexylisocyanide)gold(I) bis(phenylene-1,2-dithiolato)aurate(III)

There total 2 articles about bis(cyclohexylisocyanide)gold(I) bis(phenylene-1,2-dithiolato)aurate(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 31.0%

dichloromethane (75-09-2) + (cyclohexylisocyanide)gold(I) chloride (43067-26-1) + Benzene-1,2-dithiol (17534-15-5) → bis(cyclohexylisocyanide)gold(I) bis(phenylene-1,2-dithiolato)aurate(III) (439867-23-9) + ((C6H11CN)Au2(S2C6H4))2*2Au(NCC6H11)(C(NHC6H11)2)Cl*2CH2Cl2=((C6H11CN)Au2(S2C6H4))2(Au(NCC6H11)(C(NHC6H11)2)Cl)2*2CH2Cl2

Guidance literature:

With NaOMe; In methanol; dichloromethane; under N2 atm. (cHexNC)AuCl was reacted with NaOMe and C6H4(SH)2 in MeOH-CH2Cl2 at 20°C for 1 h with stirring; react. mixt. was evapd. to dryness under vac., residue was extd. with CH2Cl2 and layered with pentane;

DOI:10.1021/om020149e

Reference yield: 31.0%

(cyclohexylisocyanide)gold(I) chloride (43067-26-1) + Benzene-1,2-dithiol (17534-15-5) → bis(cyclohexylisocyanide)gold(I) bis(phenylene-1,2-dithiolato)aurate(III) (439867-23-9)

Guidance literature:

With MeONa; In methanol; dichloromethane; all manipulations under dry N2; thiol treated with MeONa in dry MeOH, this soln. added to soln. of Au complex in CH2Cl2 with stirring at room temp. for 1 h; solvents removed in vac., residue extd. with CH2Cl2, crystd. at -20°C (or by diffusion of pentane vapor at this temp.), elem. anal.;

DOI:10.1515/znb-2002-0808

upstream raw materials:

dichloromethane

(cyclohexylisocyanide)gold(I) chloride

Benzene-1,2-dithiol