trans-bis(o-tolunitrile)dichloroplatinum(II)

Base Information

Chemical Name:trans-bis(o-tolunitrile)dichloroplatinum(II)
CAS No.:146143-87-5
Molecular Formula:C₁₆H₁₄Cl₂N₂Pt
Molecular Weight:500.287
Hs Code.:

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Chemical Property of trans-bis(o-tolunitrile)dichloroplatinum(II)

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Technology Process of trans-bis(o-tolunitrile)dichloroplatinum(II)

There total 2 articles about trans-bis(o-tolunitrile)dichloroplatinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.0%

: 10025-99-7
potassium tetrachloroplatinate(II)

: 529-19-1
2-Methylbenzonitrile

: 146143-87-5,107002-49-3
cis-bis(o-tolunitrile)dichloroplatinum(II)

: 146143-87-5,107002-49-3
trans-bis(o-tolunitrile)dichloroplatinum(II)

Guidance literature:: In water; stirred at 60°C for 6 h with an excess of o-tolunitrile, cooled to room temp., extd. (CH2Cl2), pumped to dryness; residue treated with hot benzene, filtered, washed (Et2O), dried under vacuo (gave the cis-isomer), benzene soln. evaporated to dryness (reduced pressure), treated (petroleum ether), filtered, washed (Et2O), dried under vacuo (trans-isomer); elem. anal.;
DOI:10.1016/S0020-1693(00)84996-8

Reference yield: 42.0%

: 10025-99-7
potassium tetrachloroplatinate(II)

: 529-19-1
2-Methylbenzonitrile

: 146143-87-5,107002-49-3
cis-bis(o-tolunitrile)dichloroplatinum(II)

: 146143-87-5,107002-49-3
trans-bis(o-tolunitrile)dichloroplatinum(II)

Guidance literature:: In water; stirred at 60°C for 6 h with an excess of o-tolunitrile, cooled to room temp., extd. (CH2Cl2), pumped to dryness; residue treated with hot benzene, filtered, washed (Et2O), dried under vacuo (gave the cis-isomer), benzene soln. evaporated to dryness (reduced pressure), treated (petroleum ether), filtered, washed (Et2O), dried under vacuo (trans-isomer); elem. anal.;
DOI:10.1016/S0020-1693(00)84996-8

Reference yield: 84.0%

: 146143-87-5,107002-49-3
cis-bis(o-tolunitrile)dichloroplatinum(II)

: 107-07-3
2-chloro-ethanol

: 148684-51-9,148632-23-9
{PtCl₂(NC(C₆H₄CH₃)OCH₂CH₂)2}

Guidance literature:: With LiC₄H₉; In tetrahydrofuran; hexane; under N2; treating a soln. of ClCH2CH2OH (excess) in THF at 0°C with LiC4H9 in hexane; addn. of 1/2 equivalent of cis-(PtCl2(NCC6H4CH3-o)2); stirring after 5 min for 10 min; warming to room temperature;; taking to dryness under reduced pressure; treating with CH3OH; filtration; washing with ether; drying under vac.; elem. anal.;;
DOI:10.1039/DT9930000959