2-propenoic acid, 3-(4-methoxyphenyl)-2-methyl-, butyl ester

Base Information

• Chemical Name: 2-propenoic acid, 3-(4-methoxyphenyl)-2-methyl-, butyl ester
• CAS No.: 183011-14-5
• Molecular Formula: C₁₅H₂₀O₃
• Molecular Weight: 248.322
• Mol file: 183011-14-5.mol

Synonyms:

Chemical Property of 2-propenoic acid, 3-(4-methoxyphenyl)-2-methyl-, butyl ester

Chemical Property:

• Vapor Pressure: 0mmHg at 25°C

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-propenoic acid, 3-(4-methoxyphenyl)-2-methyl-, butyl ester

There total 3 articles about 2-propenoic acid, 3-(4-methoxyphenyl)-2-methyl-, butyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-methoxy-benzaldehyde (123-11-5) + 2-methyl-butyl acrylate (97-88-1,9003-63-8) → C15H20O3 (183011-14-5) + C15H22O3 (1253739-47-7)

Guidance literature:

With bis(acetylacetonate)nickel(II); dicarbonylacetylacetonato rhodium (I); oxygen; potassium carbonate; In water; toluene; at 150 ℃; for 24h;

DOI:10.1016/j.tetlet.2010.08.040

Reference yield:

1-bromo-4-methoxy-benzene (104-92-7) + 2-methyl-butyl acrylate (97-88-1,9003-63-8) → C15H20O3 (183011-14-5) + n-butyl 2-(4-methoxybenzyl)acrylate

Guidance literature:

With palladium diacetate; potassium carbonate; 2-diphenylphosphino-2'-methylbiphenyl; In N,N-dimethyl-formamide; at 135 ℃; for 1h; Inert atmosphere;

DOI:10.1016/j.tetlet.2009.07.052

Reference yield:

1-bromo-4-methoxy-benzene (104-92-7) + 2-methyl-butyl acrylate (97-88-1,9003-63-8) → C15H20O3 (183011-14-5) + n-butyl 2-(4-methoxybenzyl)acrylate + (Z)-2-(4-Methoxy-benzyl)-3-(4-methoxy-phenyl)-acrylic acid butyl ester

Guidance literature:

With palladium diacetate; potassium carbonate; 2-diphenylphosphino-2'-methylbiphenyl; In N,N-dimethyl-formamide; at 135 ℃; for 24h; Inert atmosphere;

DOI:10.1016/j.tetlet.2009.07.052

upstream raw materials:

1-bromo-4-methoxy-benzene

2-methyl-butyl acrylate

4-methoxy-benzaldehyde

Refernces

• 1、 Nadri, Shirin,Joshaghani, Mohammad,Rafiee, Ezzat. "Selective arylation of 1,1-disubstituted olefins using a biphenyl-based phosphine in Heck coupling reactions". experimental part. p. 5470 - 5473. Retrieved 2010/01/11.