[(η(4)-cyclooctadiene)Rh(κ(2)-As,P-Cy2AsCH2PCy2)]PF6

Base Information

Chemical Name:[(η(4)-cyclooctadiene)Rh(κ(2)-As,P-Cy2AsCH2PCy2)]PF6
CAS No.:206752-54-7
Molecular Formula:C₃₃H₅₈AsPRh*F₆P
Molecular Weight:808.589
Hs Code.:

Synonyms:

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Chemical Property of [(η(4)-cyclooctadiene)Rh(κ(2)-As,P-Cy2AsCH2PCy2)]PF6

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Technology Process of [(η(4)-cyclooctadiene)Rh(κ(2)-As,P-Cy2AsCH2PCy2)]PF6

There total 1 articles about [(η(4)-cyclooctadiene)Rh(κ(2)-As,P-Cy2AsCH2PCy2)]PF6 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 12092-47-6
di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium

: 26042-63-7
silver(I) hexafluorophosphate

: 206752-72-9
Cy₂AsCH₂PCy₂

: 206752-54-7
[(η(4)-cyclooctadiene)Rh(κ(2)-As,P-Cy2AsCH2PCy2)]PF6

Guidance literature:: In dichloromethane; byproducts: AgCl; Ar-atmosphere; stirring soln. of Rh-complex and P/As-ligand for 10 min at room temp., addn. of soln. of AgPF6, stirring for 1 h under exclusion of light; filtration off of AgCl, evapn., crystn. (MeOH, -60°C), collection, washing (pentane), drying; elem. anal.;
DOI:10.1021/om971085o

Reference yield: 94.0%

: 186581-53-3,908094-01-9,334-88-3
diazomethane

: 206752-54-7
[(η(4)-cyclooctadiene)Rh(κ(2)-As,P-Cy2AsCH2PCy2)]PF6

: 206752-60-5
[(η(4)-cyclooctadiene)Rh(κ(2)-C,P-CH2As(Cy)2CH2PCy2)]PF6

Guidance literature:: In tetrahydrofuran; diethyl ether; byproducts: N2; Ar-atmosphere; addn. of excess of diazomethane (ether) to soln. of Rh-complex (THF) at -30°C, warming to room temp., stirring for 30 min; evapn., extn. (CH2Cl2), evapn., washing (pentane:ether 4:1, pentane), drying; elem. anal.;
DOI:10.1021/om971085o

Reference yield: 93.0%

: 206752-54-7
[(η(4)-cyclooctadiene)Rh(κ(2)-As,P-Cy2AsCH2PCy2)]PF6

: 143-66-8
sodium tetraphenyl borate

: 206752-68-3
[(η(4)-cyclooctadiene)Rh(κ(2)-As,P-Cy2AsCH2PCy2)][BPh4]

Guidance literature:: In methanol; Ar-atmosphere; excess of NaBPh4, stirring for 20 min at room temp. (pptn.); collection, washing (MeOH, pentane), drying; elem. anal.;
DOI:10.1021/om971085o